Highly porous nitrogen-doped polyimine-based carbons with adjustable microstructures for CO2 capture

被引：0

作者：

Wang, Jiacheng ^{[1
,2
]}

Senkovska, Irena ^{[2
]}

Oschatz, Martin ^{[2
]}

Lohe, Martin R. ^{[2
]}

Borchardt, Lars ^{[2
]}

Heerwig, Andreas ^{[2
]}

Liu, Qian ^{[1
]}

Kaskel, Stefan ^{[2
]}

机构：

[1] State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, 1295 Dingxi Road, Shanghai 200050, China

[2] Department of Inorganic Chemistry, Dresden University of Technology, Bergstraße 66, 01069 Dresden, Germany

来源：

Journal of Materials Chemistry C | 2013年 / 1卷 / 36期

关键词：

Activation temperatures - Adsorption ratio - Adsorption selectivity - High pore volumes - High specific surface area - Micropore volumes - Micropore-size distribution - Nitrogen-doped;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A series of highly porous nitrogen doped porous carbons (NPCs) have been successfully prepared using a novel porous polyimine as the precursor. The resulting NPCs have a high specific surface area of up to 3195 m2 g-1, high pore volume and micropore volume (up to 1.58 and 1.38 cm3 g-1, respectively), narrow micropore size distributions, and adjustable nitrogen (1.52-5.05 wt%) depending on the activation temperatures (600-750 °C). The CO2 uptakes of the NPCs prepared at higher temperatures (700-750 °C) are lower than those prepared at milder conditions (600-650 °C). At 1 bar, NPC-650 demonstrates the best CO2 capture performance and could efficiently adsorb CO2 molecules of 3.10 mmol g-1 (136 mg g-1) and 5.26 mmol g-1 (231.3 mg g-1), at 25 and 0 °C, respectively. The NPCs also show good a initial CO2/N2 adsorption selectivity of up to 23.4 and an adsorption ratio of CO2/N 2 (6.6) at 1 bar. Meanwhile, these NPCs exhibit a high stability and facile regeneration/recyclability without evident loss of the CO2 capture capacities. © 2013 The Royal Society of Chemistry.

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页码：10951 / 10961