Formation of bromate in UV/Cl2, UV/NH2Cl and UV/ClO2 combining processes

被引:0
|
作者
Huang, Xin [1 ]
Gao, Nai-Yun [2 ]
Ding, Guo-Ji [1 ]
Lu, Ning [3 ]
机构
[1] School of Environment and Chemical Engineering, Shanghai University, Shanghai 200444, China
[2] State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China
[3] Shanghai Engineering Research Center of Urban Water Resources, Shanghai 200082, China
来源
Tumu Jianzhu yu Huanjing Gongcheng/Journal of Civil, Architectural and Environmental Engineering | 2010年 / 32卷 / 06期
关键词
Acidic conditions - Alkaline conditions - Bromate - Bromate formation - Chloramines - Chlorine dioxides - Combining process - Reverse effects;
D O I
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中图分类号
学科分类号
摘要
H2O-Br- -Cl2/NH2Cl/ClO2 systems. It is found that partial bromide ion was oxidized to BrO3- by Cl2/UVC. NH3 can inhibit the forming of bromate effectively, and no production of bromate is observed by NH2Cl/UVC. The bromate formation capability of ClO2/UV system is weaker than that of the Cl2/UV. Furthermore, the amount of bromate produced in ClO2/UVC is larger than that in ClO2/UVA. Both the formation of bromate and the decomposition of chlorine dioxide are improved in acidic conditions, whereas alkaline conditions lead to reverse effects.
引用
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页码:132 / 136
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