Quaternary ammonium monomer grafting polymerization under ultraviolet irradiation and adsorption of polypropylene nonwovens

被引:0
|
作者
Song, Huan [1 ,4 ,5 ]
Liu, Ying [2 ]
Shi, Xiaoli [1 ,3 ]
Zhang, Hongbo [1 ,4 ,5 ]
Pan, Zhijuan [1 ,4 ,5 ]
Zhu, Xinsheng [1 ,4 ,5 ]
机构
[1] Faculty of Clothing and Textile Engineering, Soochow University, Suzhou 215021, China
[2] Suzhou Institute, China University of Science and Technology, Suzhou 215123, China
[3] College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
[4] National Engineering Laboratory for Modern Silk (Suzhou), Suzhou 215123, China
[5] Nantong Textile Institute, Soochow University, Nantong 226004, China
来源
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2013年 / 29卷 / 07期
关键词
Adsorptive separation - Ammonium chloride - Fourier transform infra reds - Microstructure and properties - Polypropylene nonwoven fabrics - Polypropylene nonwovens - Regeneration - Ultraviolet irradiations;
D O I
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中图分类号
学科分类号
摘要
Using gamma-methacrylamidopropyl trimethyl ammonium chloride (MAPTAC) as initiator, the ultraviolet-irradiated grafting polymerization and dye adsorption of polypropylene nonwovens were carried out. The microstructure and properties of the resulted fabrics were characterized through Fourier transform infrared, thermogravimetry, and scanning electron microscopy. The results show that the quaternary ammonium monomer is successfully grafted onto the surface of polypropylene fabrics. The dye removals reach 95% for the fabric with the grafting yield of 89.6% at 35°C, 45°C and 50°C respectively. The desorption process of adsorbed fabric was realized by the sequential immersion of cationic surfactant-ethanol. The grafted fabrics can be applied for the dye adsorption repeatedly over 10 times with the dye removal degree over 99% each.
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页码:52 / 55
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