Face-to-Face Gold Porphyrins

被引：0
作者：
Sorge, Lukas [1 ]
Sikora, Philipp [1 ]
Heinze, Katja [1 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Dept Chem, D-55128 Mainz, Germany
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 45期
关键词：
VISIBLE-LIGHT PHOTOREDOX; EXCITED-STATE DYNAMICS; GAUSSIAN-BASIS SETS; ELECTRON-TRANSFER; AU-II; COFACIAL DIPORPHYRINS; MONONUCLEAR GOLD(II); MOLECULAR-STRUCTURES; OXIDATIVE ADDITION; ENERGY-TRANSFER;
D O I：
10.1021/acs.inorgchem.4c02421
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The interaction of square-planar metal complexes through space is of fundamental interest and relevant for the potential cooperative catalysis of two metal complex sites. In order to elucidate gold/gold, gold/porphyrin, and porphyrin/porphyrin interactions in the formal oxidation states +III and +II (after reduction) and in the excited triplet state after light excitation, a Pacman bis(gold(III)) complex [Au2(DPD)][PF6]2 with square-planar face-to-face gold(porphyrin) moieties has been prepared and characterized. Absorption and luminescence spectroscopy, cyclic voltammetry, and EPR spectroscopy on [Au2(DPD)] n+ and a mononuclear reference are complemented by DFT and TDDFT calculations.
引用
收藏
页码：21742 / 21752
页数：11
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