Microstructures and properties of CN films grown by dielectric barrier discharge plasma enhanced chemical vapor deposition

被引：0

作者：

Zhang, Lianlian ^{[1
,2
]}

Liu, Yanhong ^{[1
]}

Niu, Jinhai ^{[2
]}

Liu, Dongping ^{[2
]}

机构：

[1] School of Physics and Optoelectronic Technology of Dalian University of Technology

[2] Institute of Optoelectronic Technology, Dalian Nationalities University

来源：

Zhenkong Kexue yu Jishu Xuebao/Journal of Vacuum Science and Technology | 2009年 / 29卷 / 05期

关键词：

AFM; CN film; Dielectric barrier discharge; Film structure; FTIR; Raman;

D O I：

10.3969/j.issn.1672-7126.2009.05.05

中图分类号：

学科分类号：

摘要：

The carbon nitride films were grown by dielectric barrier discharge plasma enhanced chemical vapor deposition (DBD-PECVD) with gas-mixtures of CH4/N2, C2H2/N2 and C2H4/N2, respectively, on silicon substrates. The microstructures and properties of the CN films were characterized with Fourier transform Infrared spectroscopy (FTIR), Raman spectroscopy and atomic force microscopy (AFM). The influence of the film growth conditions on the film quality was studied. Diamond-like structures and C-N bonds were observed in the films. The results show that the type of the gas mixtures and the discharge pressure strongly affect the deposition rate and the surface roughness. For example, the film deposited in the CH4/N2 gas mixture shows the lowest deposition rate and the least H contents of the three gas mixtures, whereas the one in the C2H2/N2 shows the highest deposition rate. The CN films deposited with CH4/N2 gas mixture are smoother than those deposited with both C2H2/N2 and C2H4/N2, gas mixtures.

引用

页码：479 / 483

页数：4

共 17 条

[1] Liu A.Y., Cohen M.L., Science, 245, (1989)
[2] 17, 4, (2007)
[3] 25, 3, (2006)
[4] Alvarez F., Victoria N.M., Hammer P., Freire F.L., Et al., Applied Physics Letter, 73, (1998)
[5] Chen Z.Y., Zhao J.P., Yano T., Et al., J. Vac. Sci and Technol., A20, (2002)
[6] Chena K.-S., Weib T.-C., Lia M.-S., Et al., Radiation Physics and Chemistry, 76, (2007)
[7] 31, 5, (2003)
[8] Pereira J., Geraud-Grenier I., Massereau-Guilbaud V., Et al., Surface & Coatings Technology, 200, (2006)
[9] 28, 3, (2008)
[10] (2005)

← 1 2 →