Hydration characteristics of intermediate-calcium based cementitious materials from red mud and coal gangue

被引:0
|
作者
Zhang, Na [1 ]
Liu, Xiaoming [2 ]
Sun, Henghu [1 ,3 ]
机构
[1] Green Construction Materials and Circulation Economy Center, Architectural Design and Research Institute of Tsinghua University Co., Ltd., Beijing 100084, China
[2] School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
[3] Pacific Resources Research Center, University of the Pacific, Stockton, CA 95211, United States
来源
Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research | 2014年 / 28卷 / 05期
关键词
Cementitious materials - Coal gangues - Hydration characteristics - Hydration process - Hydration products - Inorganic non-metallic materials - Polymerization degree - Red mud;
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中图分类号
学科分类号
摘要
In order to deep understand the hydration characteristics of red mud-coal gangue based intermediate-calcium cementitious materials, XRD, IR, TG-DTA and MIP techniques were used to investigate the hydration products and pore structure of the hardened pastes, which formed after a hydration process of the red mud- coal gangue based intermediate-calcium cementitious materials. The results show that the hydration products mainly are C-S-H gel, ettringite and calcium hydroxide. As the dominant products, C-S-H gel and ettringite are principally responsible for the strengthening of the intermediate-calcium cementitious materials. By hydration for 1 d to 90 d, the content of calcium hydroxide increases at the initial stage and later decreases. With the progress of hydration process, the polymerization between Si-OH bonds tends to be easier, resulting in an increasing of polymerization degree of the hydration products. The red mud-coal gangue based intermediate-calcium cementitious materials with CaO/SiO2 ratios of 0.95 and 1.04 possess good pore structure of the hardened pastes, while the pore structure of the hardened paste for the material with CaO/SiO2 ratio of 1.13 is relatively poor. © Copyright.
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页码:325 / 332
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