Preparation of lignin-polyethyleneimine and its sorption properties for Cu2+ ion

被引:0
作者
机构
[1] College of Material Science and Engineering, Northeast Forestry University
[2] Harbin Center for Disease Control and Prevention
来源
Fang, G.-Z. (fanggz_0@163.com) | 1600年 / Journal of Functional Materials卷 / 45期
关键词
Lignin; Polyethyleneimine; Sorption;
D O I
10.3969/j.issn.1001-9731.2014.08.031
中图分类号
学科分类号
摘要
In this paper the sorbent of lignin-polyethyleneimine (lignin-PEI) was successfully synthesized by means of crosslinking lignin and polyethyleneimine (PEI) by glutaraldehyde. We characterized lignin-PEI by SEM, XRD, FT-IR and XPS, then investigated the use of lignin-PEI for the removal of Cu2+ from water. These results indicated that the nitrogen content of prepared lignin-PEI was 10.61 wt% at lignin, PEI and GA reaction ratio m(g):V(mL):V(mL) of 2:5:20, at 25°C for 2 h. We found sorption isotherms for lignin-PEI better fitted Langmuir equation. Sorption of Cu2+ ion on lignin-PEI followed pseudo second-order kinetics. The maximum sorption capacity was 54.15 mg/g for Cu2+ ion.
引用
收藏
页码:08143 / 08147
页数:4
相关论文
共 20 条
  • [1] Zhou Y.T., White C.B., Nie H.L., Et al., Adsorption mechanism of Cu<sup>2+</sup> from aqueous solution by chitosan-coated magnetic nanoparticles modified with α-ketoglutaric acid, Colloids and Surfaces B: Biointerfaces, 74, 1, pp. 244-252, (2009)
  • [2] Silva Filho E.C., Lima L.C.B., Silva F.C., Et al., Immobilization of ethylene sulfide in aminated cellulose for removal of the divalent cations, Carbohydrate Polymers, 92, 2, pp. 1203-1210, (2013)
  • [3] Li G.L., Zhao Z.S., Liu J.Y., Et al., Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica, Journal of Hazardous Materials, 192, 1, pp. 277-283, (2011)
  • [4] Choi M.J., Jang J., Heavy metal ion adsorption onto polypyrrole-impregnated porous carbon, Journal of Colloid and Interface Science, 325, 1, pp. 287-289, (2008)
  • [5] Lv J., Luo L., Zhang J., Et al., Adsorption of mercury on lignin: combined surface complexation modeling and X-ray absorption spectroscopy studies, Environmental Pollution, 162, pp. 255-261, (2012)
  • [6] Rahikainen J.L., Martin-Sampedro R., Heikkinen H., Et al., Inhibitory effect of lignin during cellulose bioconversion: the effect of lignin chemistry on non-productive enzyme adsorption, Bioresource Technology, 133, pp. 270-278, (2013)
  • [7] Zhang J., Lin X., Luo X., Et al., A modified lignin adsorbent for the removal of 2, 4, 6-trinitrotoluene, Chemical Engineering Journal, 168, 3, pp. 1055-1063, (2011)
  • [8] Kriaa A., Hamdi N., Srasra E., Removal of Cu(II) from water pollutant with Tunisian activated lignin prepared by phosphoric acid activation, Desalination, 250, 1, pp. 179-187, (2010)
  • [9] Albadarin A.B., Al-Muhtaseb A.H., Al-Laqtah N.A., Et al., Biosorption of toxic chromium from aqueous phase by lignin: mechanism, effect of other metal ions and salts, Chemical Engineering Journal, 169, 1, pp. 20-30, (2011)
  • [10] Guo X., Zhang S., Shan X., Adsorption of metal ions on lignin, Journal of Hazardous Materials, 151, 1, pp. 134-142, (2008)