Simulation and optimization of extractive distillation for separation of azeotropic benzene/cyclohexane system

被引:0
作者
Zhai, Jian [1 ]
Liu, Yuliang [1 ]
Li, Lumin [1 ]
Wang, Qiuyuan [2 ]
Sun, Lanyi [1 ]
机构
[1] State Key Laboratory of Heavy Oil Processing in China University of Petroleum, Qingdao, 266580, Shandong
[2] Qingdao Soda Ash Industrial New Material and Technology Company Limited, Qingdao, 266043, Shandong
来源
Huagong Xuebao/CIESC Journal | 2015年 / 66卷 / 09期
基金
中国国家自然科学基金;
关键词
Dividing wall column; Energy savings; Extraction; Genetic algorithm; Heat integrated pressure-swing; Optimization;
D O I
10.11949/j.issn.0438-1157.20150781
中图分类号
学科分类号
摘要
The separation of benzene and cyclohexane with furfural as entrainer was studied using conventional extractive distillation, extractive dividing wall column distillation and heat integrated pressure-swing extractive distillation. The three whole processes were simulated by commercial process simulator Aspen Plus V8.4. The sensitive analyses of all steady-state designs were carried out and the optimal flow sheets with minimum energy requirements have been established using the multi-objective genetic algorithm with constrains. Compared with the conventional configuration, the extractive dividing wall column distillation and heat integrated pressure-swing extractive distillation process with minimum heat duty of the reboiler presented the energy savings of 21.5% and 15.7%, respectively. The economic analysis was carried out to evaluate the economic feasibility of the three processes. The results clearly demonstrated that when compared with the conventional extractive distillation process, the total annual cost was reduced by 6.0% in the extractive dividing wall column and increased by 50.8% in the heat integrated pressure-swing extractive distillation, which provided a theory basis and design reference for the industrial design for extractive distillation process to separate azeotropic benzene and cyclohexane system. © All right reserved.
引用
收藏
页码:3570 / 3579
页数:9
相关论文
共 26 条
[1]  
Li C., Zhang X., Zhang Z., Zhang W., Separating benzene and cyclohexane by batch extractive distillation, Chemical Industry and Engineering, 22, 6, pp. 422-426, (2005)
[2]  
Villaluenga J.P.G., Tabe-Mohammadi A., A review on the separation of benzene/cyclohexane mixtures by pervaporation processes, Journal of Membrane Science, 169, 2, pp. 159-174, (2000)
[3]  
Modla G., Energy saving methods for the separation of a minimum boiling point azeotrope using an intermediate entrainer, Energy, 50, 1, pp. 103-109, (2013)
[4]  
Zhang Z., Liu L., Li W., Chen L., Effect of ternary mixed solvent or separation of benzene-cyclohexane by extractive distillation, CIESC Journal, 62, 9, pp. 2541-2545, (2011)
[5]  
Berg L., Separation of benzene from close boiling hydrocarbons by extractive distillation
[6]  
Yin W., Ding S., Xia S., Ma P., Huang X., Zhu Z., Cosolvent selection for benzene-cyclohexane separation in extractive distillation, Journal of Chemical & Engineering Data, 55, 9, pp. 3274-3277, (2010)
[7]  
Kumar U.A., Mohan R., Quinary and eight-component liquid-liquid equilibria of mixtures of alkanes, aromatics, and solvent (furfural), Journal of Chemical & Engineering Data, 58, 8, pp. 2194-2201, (2013)
[8]  
Zhang Z., Xu S., Li X., Zhang W., Study on separating benzene-cyclohexane by regular batch extractive distillation, Chemical Engineering (China), 34, 4, pp. 5-8, (2006)
[9]  
Zhang Z., Xu S., Li X., Zhang W., Influence of temperature on solvent selectivity for extractive distillation, Journal of Chemical Industry and Engineering (China), 55, 10, pp. 1740-1742, (2005)
[10]  
Gao X., Liu W., Chen H., Huang K., Wang S., A simulation based study of externally heat integrated reactive distillation system, CIESC Journal, 63, 2, pp. 538-544, (2012)