Structural, linear optical, second and third-order nonlinear optical properties of two halogenated chalcone derivatives containing thiophene moiety

被引：0
作者：
Naik V.S. [1 ,4 ]
Patil P.S. [2 ]
Gummagol N.B. [2 ]
Wong Q.A. [3 ]
Quah C.K. [3 ]
Jayanna H.S. [1 ]
机构：
[1] Department of Physics, Kuvempu University, Shankaraghatta, 577 451, Karnataka
[2] Department of Engineering Physics, K.L.E. Institute of Technology, Hubballi, 580 027, Karnataka
[3] X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, Penang
[4] Department of Physics, Government First Grade College, Kumta, 581 343, Karnataka
来源：
Chemical Physics Letters | 2020年 / 761卷
关键词：
Chalcone derivatives; Density Functional Theory (DFT); Nonlinear optical (NLO) materials; Second Harmonic Generation (SHG); Single crystal X-ray diffraction; Z-scan technique;
D O I：
10.1016/j.cplett.2020.138051
中图分类号：
学科分类号：
摘要：
Two halogenated chalcones B3B2SC and C3B2SC were synthesized for NLO applications. Single-crystal X-ray diffraction, spectroscopic (NMR and FT-IR), thermal and DFT studies were performed. Both the crystals are crystallized in the monoclinic non-centrosymmetric Pn space group. The SHG efficiency of both the chalcones is higher than urea. The third-order NLO parameters, optical limiting and optical switching properties of the chalcones were investigated by Z-scan method using a CW laser at 532 nm. The experimental and computational linear and nonlinear optical studies revealed that both the chalcone are promising materials for NLO applications. © 2020 Elsevier B.V.
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  • [1] Papadopoulos M.G., Sadlej A.J., Leszczynski J., Non-linear Optical Properties of Matter, (2006)
  • [2] Prasad P.N., DJW, Introduction to nonlinear optical effects in molecules and polymers, (1990)
  • [3] Chemla D.S., Zyss J., Nonlinear Optical Properties of Organic Molecular Crystals, 12, (1987)
  • [4] Bardan J., Hierle R., Perigaud A., Zyss J., Williams D.J., Nonlinear Optical Properties of Organic Molecules and Polymeric Materials, American Chemical Symposium Series, 233, (1993)
  • [5] Anis M., Muley G.G., Hakeemd A., Shirsat M.D., Hussaini S.S., Exploring the influence of carboxylic acids on nonlinear optical (NLO) and dielectric properties of KDP crystal for applications of NLO facilitated photonic devices, Opt. Mater., 46, pp. 517-521, (2015)
  • [6] Kamath L., Manjunatha K.B., Shettigar S., Umesh G., Narayana B., Samshuddin S., Sarojini B.K., Investigation of third-order nonlinear and optical power limiting properties of terphenyl derivatives, Opt. Laser Technol., 56, pp. 425-429, (2014)
  • [7] Saravanan M., Senthila A., Rajasekar S.A., Crystal growth, solubility, structural, optical, thermal, mechanical and electrical studies of L-arginium adipate: an organic nonlinear optical material, Optik-Int. J. Light Electron Opt., 127, pp. 1372-1377, (2016)
  • [8] Menezes A.P., Jayarama A., Ng S.W., Synthesis, crystal growth and characterization of a D-π-A type novel organic nonlinear optical single crystal, J. Cryst. Growth, 402, pp. 130-137, (2014)
  • [9] Abegao L.M.G., Fonseca R.D., Santos F.A., Souza G.B., Barreiros A.L.B.S., Barreiros M.L., Alencar M.A.R.C., Mendonca C.R., Silva D.L., De Boni L., Rodrigues J.J., Second- and third-order nonlinear optical properties of unsubstituted and mono-substituted chalcones, Chem. Phys. Lett., 648, pp. 91-96, (2016)
  • [10] Menezes A.P., Jayarama A., Ng S.W., Crucial role of molecular planarity on the second order nonlinear optical property of pyridine based chalcone single crystals, J. Mol. Struct., 1088, pp. 85-94, (2015)
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