Preparation and properties of self-healing photochromic polyurethane composite fabric

被引：0
作者：
Li, Han [1 ]
Guo, Yang [1 ]
Bai, Song [1 ]
Wu, Huanling [1 ]
Lin, Ling [1 ]
Mao, Haiyan [1 ]
机构：
[1] School of Textile & Clothing, Yancheng Institute of Technology, Yancheng
来源：
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2024年 / 41卷 / 08期
基金：
中国国家自然科学基金;
关键词：
composite fabric; photochromism; polyurethane; recycling; self-healing property;
D O I：
10.13801/j.cnki.fhclxb.20231214.004
中图分类号：
学科分类号：
摘要：
In order to improve the durability of photochromic coated fabrics, the photochromic microcapsules (PM) and zwitterionic polyurethane (ZPU) were used to prepare PM/ZPU films, which were then hot-pressed onto cotton fabrics to obtain the self-healing PM/ZPU composite fabrics. The structure and morphology of PM/ZPU composite fabric were characterized, and the photochromic properties, self-healing and recycling ability of PM/ZPU composite fabric were discussed in detail. The results show that the maximum absorption wavelength of PM/ZPU composite fabric changes from 470 nm to 530 nm, the color changes from yellow-orange to reddish-brown, and the fabric has good fatigue resistance. Based on the dynamic reversibility of zwitterionic, the scratches of PM/ZPU composite fabric can be completely repaired at 80℃, and the bond strength of the fractured composite fabric reaches 1.47 MPa at 60℃, showing excellent self-healing properties. The coating on the waste fabric can be recycled and reused by a simple dissolution method, and the PM/ZPU composite fabric can still be prepared with good photochromic properties. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
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页码：4189 / 4199
页数：10
相关论文
共 27 条
  • [1] ZENG Chanjuan, JI Xiaoqian, LIU Wenwen, Et al., Preparation of 10, 12-25 carbodiacetylenic acid modified polyurethane/polyepoxy-ethylene fiber film and its UV/thermochromic properties, Journal of Textile Research, 39, 8, pp. 9-14, (2018)
  • [2] HUANG N, YAN X X, ZHAO W T., Influence of photochromic microcapsules on properties of waterborne coating on wood and metal substrates, Coatings, 12, 11, (2022)
  • [3] WANG X Y, MA X H, CUI S Q, Et al., Preparation of a photochromic diarylethene microcapsule with high fatigue resistant and printed on cotton fabric, Materials Letters, 346, (2023)
  • [4] CHEN Xin, FEI Liang, YIN Yunjie, Et al., Photochromic microcapsules of polystyrene wall materials were prepared by solvent volatilization, Fine Chemicals, 40, 1, pp. 63-68, (2023)
  • [5] HUO Y N, ZHOU J X, XU Z S, Et al., Preparation and properties of water-based photochromic polyurethane coatings containing Er(III)-doped WO<sub>3</sub>, Surface and Interface Analysis, 55, 4, pp. 288-295, (2023)
  • [6] GAO Y, ZHANG W H, HAN N, Et al., Cotton fabric containing photochromic microcapsules combined thermal energy storage features, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 648, (2022)
  • [7] BAO Lihong, SUN Jiaxun, Preparation and properties of waterborne photochromic polyurethane, Coatings Industry, 45, 12, pp. 7-13, (2015)
  • [8] GUO Jing, HU Fan, ZHANG Hongjuan, Et al., Preparation method and application of photochromic textiles, Shanghai Textile Science, 50, 12, pp. 8-12, (2022)
  • [9] BAO B, FAN J, WANG W, Et al., Photochromic cotton fabric prepared by spiropyran-ternimated water polyurethane coating, Fibers and Polymers, 21, 4, pp. 733-742, (2020)
  • [10] DING Zihan, QU Hua, Preparation and properties of waterborne polyurethane waterproof permeable coating fabric modified by nano silica, Journal of Textile Research, 42, 3, pp. 130-135, (2021)
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