Recent advances in metal organic frameworks mixed matrix membranes for water treatment

被引:0
|
作者
Zhao D. [1 ]
机构
[1] College of Civil Engineering and Architecture, Nanyang Normal University, Nanyang
来源
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2021年 / 40卷 / 02期
关键词
Membranes; Metal organic frameworks; Permeability; Selectivity; Separation;
D O I
10.16085/j.issn.1000-6613.2020-0744
中图分类号
学科分类号
摘要
Metal organic frameworks (MOFs) synthesized by self-assembly of inorganic metal ions and organic ligands with high porosity and adjustable window size endow the MOFs mixed matrix membranes with both high flux and high rejection, which are expected to break the trade-off effect between permeability and selectivity of traditional membranes. This paper reviews the typical structures of MOFs, the preparation methods and the key influence factors of the performance of the MOFs mixed matrix membranes, and the principle of MOFs nanoparticles for improving the water transport and solute separation performance. Besides, the latest research progresses of the MOFs mixed matrix membranes in the fields of microfiltration/ultrafiltration, nanofiltration/reverse osmosis, and forward osmosis for water treatment are introduced. Finally, several critical issues in the future development of the MOFs mixed matrix membranes for water treatment are summarized, mainly including the controllable preparation of the membranes with high-performance and low-cost, the deep exploration of the quantitative structure-function relationship between membrane structure and performance, and the expanding of their application scopes, which have guiding significance for speeding up the industrialization process of the MOFs mixed matrix membranes. © 2021, Chemical Industry Press Co., Ltd. All right reserved.
引用
收藏
页码:1035 / 1047
页数:12
相关论文
共 74 条
  • [21] KNEBEL A, SUNDERMANN L, MOHMEYER A, Et al., Azobenzene guest molecules as light-switchable CO<sub>2</sub> valves in an ultrathin UiO-67 membrane, Chemistry of Materials, 29, 7, pp. 3111-3117, (2017)
  • [22] HU J, SUN T, LIU X, Et al., Rationally tuning the separation performances of[M<sub>3</sub>(HCOO)<sub>6</sub>] frameworks for CH<sub>4</sub>/N<sub>2</sub> mixtures via metal substitution, Microporous and Mesoporous Materials, 225, pp. 456-464, (2016)
  • [23] HE M, WANG L, LYU Y, Et al., Novel polydopamine/metal organic framework thin film nanocomposite forward osmosis membrane for salt rejection and heavy metal removal, Chemical Engineering Journal, 389, (2020)
  • [24] HE Y, TANG Y P, MA D, Et al., UiO-66 incorporated thin-film nanocomposite membranes for efficient selenium and arsenic removal, Journal of Membrane Science, 541, pp. 262-270, (2017)
  • [25] LIU X-L, LI Y-S, ZHU G-Q, Et al., An organophilic pervaporation membrane derived from metal-organic framework nanoparticles for efficient recovery of bio-alcohols, Angewandte Chemie-International Edition, 50, 45, pp. 10636-10639, (2011)
  • [26] REN Y, LI T, ZHANG W, Et al., MIL-PVDF blend ultrafiltration membranes with ultrahigh MOF loading for simultaneous adsorption and catalytic oxidation of methylene blue, Journal of Hazardous Materials, 365, pp. 312-321, (2019)
  • [27] ZHANG Y, WANG N, ZHAO C, Et al., Co(HCOO)<sub>2</sub>-based hybrid membranes for the pervaporation separation of aromatic/aliphatic hydrocarbon mixtures, Journal of Membrane Science, 520, pp. 646-656, (2016)
  • [28] YANG L, WANG Z, ZHANG J., Zeolite imidazolate framework hybrid nanofiltration (NF) membranes with enhanced permselectivity for dye removal, Journal of Membrane Science, 532, pp. 76-86, (2017)
  • [29] MA X-H, YANG Z, YAO Z-K, Et al., A facile preparation of novel positively charged MOF/chitosan nanofiltration membranes, Journal of Membrane Science, 525, pp. 269-276, (2017)
  • [30] SUN H, TANG B, WU P., Development of hybrid ultrafiltration membranes with improved water separation properties using modified superhydrophilic metal-organic framework nanoparticles, ACS Applied Materials & Interfaces, 9, 25, pp. 21473-21484, (2017)