Catalytic ozonation of pharmaceutical compounds using carbon-based catalysts

被引：0
作者：
Orge C.A. [1 ,2 ]
Graça C.A.L. [1 ,2 ]
Restivo J. [1 ,2 ]
Pereira M.F.R. [1 ,2 ]
Soares O.S.G.P. [1 ,2 ]
机构：
[1] Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, Porto
[2] ALiCE – Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, Porto
来源：
Catalysis Communications | 2024年 / 187卷
关键词：
Carbon materials; Catalytic ozonation; Pharmaceuticals; Wastewater;
D O I：
10.1016/j.catcom.2024.106863
中图分类号：
学科分类号：
摘要：
Catalytic ozonation has become one of the most promising technologies for wastewater treatment due to its high efficiency in the removal of organic pollutants. Three carbon materials (carbon nanotubes, graphene oxide and activated carbon) and five pharmaceutical compounds were selected for this study. All tested parent pollutants were easily degraded by single ozonation. In terms of mineralization, the presence of catalyst revealed to be necessary to enhance organic matter removal, and activated carbon (GAC) showing superior performance. To evaluate the effect of the water matrix, experiments were performed with ground water and wastewater and significant degradation of pollutants was achieved. © 2024 The Authors
引用
收藏
相关论文
共 41 条
[1]  
Issaka E., Amu-Darko J.N.-O., Yakubu S., Fapohunda F.O., Ali N., Bilal M., Advanced catalytic ozonation for degradation of pharmaceutical pollutants—a review, Chemosphere, 289, pp. 133208-133225, (2022)
[2]  
Ikehata K., Jodeiri Naghashkar N., Gamal El-Din M., Degradation of aqueous pharmaceuticals by ozonation and advanced oxidation processes: a review, Ozone Sci. Eng., 28, pp. 353-414, (2006)
[3]  
Gotz K., Courtier A., Stein M., Strelau L., Sunderer G., Vidaurre R., Winker M., Roig B., Chapter 8 - risk perception of pharmaceutical residues in the aquatic environment and precautionary measures, Management of Emerging Public Health Issues and Risks, pp. 189-224, (2019)
[4]  
Wang H., Zhang S., He X., Yang Y., Yang X., Van Hulle S.W.H., Comparison of macro and micro-pollutants abatement from biotreated landfill leachate by single ozonation, O3/H2O2, and catalytic ozonation processes, Chem. Eng. J., 452, pp. 139503-139515, (2023)
[5]  
Paiga P., Correia M., Fernandes M.J., Silva A., Carvalho M., Vieira J., Jorge S., Silva J.G., Freire C., Delerue-Matos C., Assessment of 83 pharmaceuticals in WWTP influent and effluent samples by UHPLC-MS/MS: hourly variation, Sci. Total Environ., 648, pp. 582-600, (2019)
[6]  
Barbosa M.O., Moreira N.F.F., Ribeiro A.R., Pereira M.F.R., Silva A.M.T., Occurrence and removal of organic micropollutants: an overview of the watch list of EU decision 2015/495, Water Res., 94, pp. 257-279, (2016)
[7]  
Iakovides I.C., Michael-Kordatou I., Moreira N.F.F., Ribeiro A.R., Fernandes T., Pereira M.F.R., Nunes O.C., Manaia C.M., Silva A.M.T., Fatta-Kassinos D., Continuous ozonation of urban wastewater: removal of antibiotics, antibiotic-resistant Escherichia coli and antibiotic resistance genes and phytotoxicity, Water Res., 159, pp. 333-347, (2019)
[8]  
Chavez A.M., Ribeiro A.R., Moreira N.F.F., Silva A.M.T., Rey A., Alvarez P.M., Beltran F.J., Removal of organic micropollutants from a municipal wastewater secondary effluent by UVA-LED photocatalytic ozonation, Catalysts, 9, pp. 472-487, (2019)
[9]  
Shokri A., Mahanpoor K., Degradation of ortho-toluidine from aqueous solution by the TiO2/O3 process, Int. J. Ind. Chem., 8, pp. 101-108, (2017)
[10]  
Wang J., Lou Y., Xu C., Song S., Liu W., Magnetic lanthanide oxide catalysts: an application and comparison in the heterogeneous catalytic ozonation of diethyl phthalate in aqueous solution, Sep. Purif. Technol., 159, pp. 57-67, (2016)
12345