Tribological Properties of Nitrogen-Containing Lubricant Additives

被引:0
|
作者
Liao J. [1 ,2 ]
Lu H. [2 ]
Dai K. [2 ]
Cao H. [3 ]
Zhao H. [2 ]
Han L. [2 ]
Xu Y. [2 ]
Fang Y. [1 ]
机构
[1] School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, Guangdong
[2] School of Chemical Engineering and Energy Technology, Dongguan University of Technology, Dongguan, 523808, Guangdong
[3] Foshan Delian Automotive Accessories Co., Ltd., Foshan, 528247, Guangdong
来源
Zhao, Hongbin (zhaohbhanlf@163.com) | 2018年 / South China University of Technology卷 / 46期
基金
中国博士后科学基金;
关键词
Corrosion resistance; Liquid paraffin; Nitrogen-containing lubricant additives; Oil solubility; Thermal stability; Tribological properties;
D O I
10.3969/j.issn.1000-565X.2018.07.010
中图分类号
学科分类号
摘要
Four environment friendly lubricant additives, namely N1, N2, N3 and N4, have been designed, synthesized and characterized. The thermal stability, oil solubility and corrosion resistance of these additives have been systematically studied. Tribological behaviors of the lubricant additives in liquid paraffin (LP) were investigated. The surfaces morphology and elementary composition of the worn scar was recorded and analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The reaction mechanism was initially discussed. It was found that the synthesized additives showed high thermal stability, excellent oil solubility and strong corrosion resistance. Among the four additives, N2 exhibited the best tribological property. For example, the maximum non-seizure load (PB) value of LP with 1.0wt% N2 was 74% higher than that of LP, the sintered load (PD) value was twice as large as that of LP. The wear scar diameter (WSD) of 1.0% N2+LP system was 54% lower than that of LP, and the friction coefficient was 28% lower than that of LP. The addition of four additives significantly reduced WSD and surface abrasions of LP. The additive participated in tribo-chemical reaction in the friction process, which effectively improved the extreme pressure, anti-wear and anti-friction performance of LP. © 2018, Editorial Department, Journal of South China University of Technology. All right reserved.
引用
收藏
页码:70 / 78
页数:8
相关论文
共 26 条
  • [1] Ouyang P., Chen Y.-H., Research and development of boron-and nitrogen-containing heterocyclic lubricating materials, Journal of Materials Science & Engineering, 32, 1, pp. 135-141, (2014)
  • [2] Liu W.-M., Xu J., Feng D.-P., Et al., The research status and prospect of synthetic lubricating oils, Tribology, 33, 1, pp. 91-104, (2013)
  • [3] Zhao C.-S., Zhang Y.-W., Li J.-C., Et al., Tribological properties and action mechanism of thiadiazole organic borate esters as additives in lithium-based grease, Tribology, 34, 3, pp. 325-332, (2014)
  • [4] Spikes H., Low-and zero-sulphated ash, phosphorus and sulphur anti-wear additives for engine oils, Lubrication Science, 20, 2, pp. 103-136, (2008)
  • [5] Yan J., Zeng X., Heide E.V.D., Et al., The tribological performance and tribochemical analysis of novel borate esters as lubricant additives in rapeseed oil<sup>☆</sup> , Tribology International, 71, 1, pp. 149-157, (2014)
  • [6] Chen B.-S., Huang W.-J., Sun X., Et al., Friction and wear characteristics of fatty acyl amino acids in mine-ral lubricating oil, Journal of Materials Science & Engineering, 29, 3, pp. 371-374, (2011)
  • [7] Xie E.-Q., Zhao X.-N., Zhang Y.-H., Et al., Lubricant extreme pressure anti-wear additives applied research progress and direction, Coal and Chemical Industry, 36, 5, pp. 25-27, (2013)
  • [8] Li Y.-M., Gu G.-W., Zhao J.-F., Study on anoxic biodegradation mechanism of several nitrogen heterocyclic compounds in coal coking wastewater, Journal of Tongji University(Natural Science Edition), 29, 6, pp. 720-723, (2001)
  • [9] Cao Y.-P., Yu L.-G., The effect of tribenyl phosphate and dibutyl phosphite as additives on the tribological behaviors of rapeseed oil, Tribology, 20, 2, pp. 119-122, (2000)
  • [10] Liu Y.-L., Liu C.-S., Wu X.-J., Et al., Synthesis and tribological behavior study of biodegradative lubricant additives, Petroleum Processing and Petrochemicals, 42, 7, pp. 54-57, (2011)