Preparation of self-modeling composite material and its selective adsorption towards crotonaldehyde in mainstream cigarette smoke

被引：0

作者：

Cao, Yi ^{[1
]}

Zhu, Huaiyuan ^{[1
]}

Liu, Xianjun ^{[1
]}

Zhou, Yu ^{[2
]}

Zhu, Ying ^{[1
]}

Zhuang, Yadong ^{[1
]}

Shen, Xiaochen ^{[1
]}

Lin, Weigang ^{[2
]}

Xiong, Xiaomin ^{[1
]}

Zhu, Jianhua ^{[2
]}

机构：

[1] Research and Development Center, China Tobacco Jiangsu Industrial Co., Ltd., Nanjing

[2] College of Chemistry and Chemical Engineering, Nanjing University, Nanjing

来源：

Acta Tabacaria Sinica | 2014年 / 20卷 / 06期

关键词：

Composite material; Crotonaldehyde; Mainstream cigarette smoke; Selective adsorption; Self-modeling;

D O I：

10.3969/j.issn.1004-5708.2014.06.003

中图分类号：

学科分类号：

摘要：

Ethyl ether was introduced in hydrothermal synthesis process when mesoporous material was prepared. An emulsion system was formed to promote self-modeling. After adding zeolite fragments into synthetic system, series of self-modeling composite porous materials were prepared which named CTN/X (X=NaA, NaZSM-5, NaY). The adsorptive ability of these composite materials when used as cigarette filter additives was investigated. Crotonaldehyde in mainstream cigarette smoke was set to be target molecule. Results showed that emulsion system was beneficial for self-modeling. Specific surface area of CTN/NaY reached 832 m2/g, and the most probable pore size of CTN/NaZSM-5 was 4.3 nm. Compared with controls, cigarettes with filters added these composite materials exhibited excellent selectively adsorptive ability to crotonaldehyde in mainstream cigarette smoke, while nicotine and tar level in test cigarette smoke changed a little. When CTN/NaY sample was used as filter additive, crotonaldehyde content in main stream cigarette smoke could be reduced by 30.4%. ©, 2014, State Tobacco Monopoly Bureau and China Tobacco Society. All right reserved.

引用

页码：12 / 20

页数：8

共 11 条

[1] Fowles J., Dybing E., Application of toxicological risk assessment principles to the chemical constituents of cigarette smoke, Tob Control, 12, 4, pp. 424-430, (2003)
[2] Green C.R., Schumacher J.N., Lloyd R.A., Et al., Comparisons of the composition of tobacco smoke and the smokes from various tobacco substitutes, Beitr Zur Tabakforsch Int, 22, 4, pp. 258-289, (2007)
[3] Stedman R.L., The chemical composition of tobacco and tobacco smoke, Chem Rev, 68, 2, pp. 153-207, (1968)
[4] Brunnemann K.D., Hoffmann D., Pyrolytic origins of gas phase constituents of cigarette smoke, Rec Adv Tob Sci, 8, pp. 103-140, (1982)
[5] Miyake T., Shibamoto T., Quantitative analysis by gas chromatography of volatile carbonyl compounds in cigarette smoke, J Chromatogr A, 693, 2, pp. 376-381, (1995)
[6] Zhu J.H., Zhou S.L., Xu Y., Et al., Ordered mesoporous materials: Novel catalyst for degradation of N'-nitrosonornicotine, Chem Lett, 32, 4, pp. 338-339, (2003)
[7] Xu J.H., Zhuang T.T., Cao Y., Et al., Improving MCM-41 as a nitrosamines trap through a one-pot synthesis, Chem Asian J, 2, 8, pp. 996-1006, (2007)
[8] Zhou C.F., Wang Y.M., Cao Y., Et al., Solvent-free surface functionalized SBA-15 as a versatile trap of nitrosamines, J Mater Chem, 16, 16, pp. 1520-1528, (2006)
[9] Gu F.N., Lin W.G., Yang J.Y., Et al., Fabrication of centimeter-sized sphere of mesoporous silica with well-defined hollow nanosphere topology and its high performance in adsorbing phenylalanine, Microporous and Mesoporous Mater, 151, pp. 142-148, (2012)
[10] Branton P.J., Liu C., McAdam K.G., Et al., A systematic improvement in filtration efficiency of aldehydes in mainstream cigarette smoke, 6, pp. 5-15, (2012)

← 1 2 →