Selective synthesis of cyclic compounds by palladium-catalyzed cyclization of propargylic esters with nucleophiles

被引：0
作者：
Yoshida M. [1 ]
机构：
[1] Faculty of Pharmaceutical Sciences, Tokushima Bunri University, 180 Yamashiro-cho, Tokushima
来源：
Yoshida, Masahiro (yoshida@ph.bunri-u.ac.jp) | 1600年 / Society of Synthetic Organic Chemistry卷 / 75期
基金：
日本学术振兴会;
关键词：
Cascade reaction; Cyclic molecules; Cyclization; Diastereoselective reaction; Nucleophiles; Oxazolidinone; Palladium; Propargylic compounds; Regioselective reaction;
D O I：
10.5059/yukigoseikyokaishi.75.38
中图分类号：
学科分类号：
摘要：
Palladium-catalyzed cyclization of propargylic esters with bis-nucleophiles is one of the useful method for the construction of cyclic molecules in one step. A variety of products could be synthesized in one step by the choice of adequately designed nucleophilic molecules. In this review, we describe a comprehensive overview of our studies on palladium-catalyzed reactions of propargylic esters with bis-nucleophiles. The reactions afforded various functionalized hetero- and carbocyclic molecules in a regio- and stereoselective manner.
引用
收藏
页码：38 / 48
页数：10
相关论文
共 50 条
  • [31] Palladium-catalyzed construction of quaternary carbon centers with propargylic electrophiles
    Franckevicius, Vilius
    TETRAHEDRON LETTERS, 2016, 57 (32) : 3586 - 3595
  • [32] Palladium-Catalyzed Coupling of Propargylic Carbonates with N-Tosylhydrazones: Highly Selective Synthesis of Substituted Propargylic N-Sulfonylhydrazones and Vinylallenes
    Chen, Zi-Sheng
    Duan, Xin-Hua
    Wu, Lu-Yong
    Ali, Shaukat
    Ji, Ke-Gong
    Zhou, Ping-Xin
    Liu, Xue-Yuan
    Liang, Yong-Min
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (25) : 6918 - 6921
  • [33] Chelated enolates of amino acid esters - Efficient nucleophiles in palladium-catalyzed allylic substitutions
    Kazmaier, U
    Zumpe, FL
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (10) : 1468 - 1470
  • [34] Concise total synthesis of (-)-frondosin B using a novel palladium-catalyzed cyclization
    Hughes, CC
    Trauner, D
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (09) : 1569 - 1572
  • [35] Synthesis of Substituted Acridines through a Palladium-Catalyzed Condensation/Cyclization/Tautomerization Sequence
    Chen, Xiangui
    YanjunXie
    Li, Cheng
    Xiao, Fuhong
    Deng, Guo-Jun
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (03) : 577 - 581
  • [36] Synthesis of isagarin, a tetracyclic naphthoquinone via a palladium-catalyzed cyclization
    Ploysuk, Chatchawan
    Kongkathip, Boonsong
    Kongkathip, Ngampong
    SYNTHETIC COMMUNICATIONS, 2007, 37 (7-9) : 1463 - 1471
  • [37] Convenient synthesis of spiroindole derivatives via palladium-catalyzed cyclization of propargyl chlorides
    Iwata, Akira
    Inuki, Shinsuke
    Oishi, Shinya
    Fujii, Nobutaka
    Ohno, Hiroaki
    TETRAHEDRON, 2015, 71 (37) : 6580 - 6585
  • [38] Synthesis of Fluorene and Indenofluorene Compounds: Tandem Palladium-Catalyzed Suzuki Cross-Coupling and Cyclization
    Liu, Tao-Ping
    Xing, Chun-Hui
    Hu, Qiao-Sheng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (16) : 2909 - 2912
  • [39] Synthesis of cyclic organosilicon compounds by palladium-catalyzed reactions of 2-silylaryl triflates
    Shintani, Ryo
    CHEMISTRY LETTERS, 2024, 53 (07)
  • [40] Palladium-catalyzed cyclocarbonylation of cyclic diaryliodoniums: Synthesis of fluorenones
    Liu, Li
    Qiang, Jian
    Bai, Shuhua
    Li, Yang
    Miao, Chunbao
    Li, Jian
    APPLIED ORGANOMETALLIC CHEMISTRY, 2017, 31 (12)
12345