Synthesis, structure and properties of nylon elastomer

被引:0
作者
Lei, Jingxin [1 ]
Guo, Dongyang [1 ]
Gao, Jun [2 ]
Zhou, Changlin [1 ]
机构
[1] State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China
[2] Chemical Engineering College of Sichuan University, Chengdu 610065, China
来源
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2014年 / 30卷 / 02期
关键词
Average molecular weight - Comprehensive properties - High-tensile strength - Low glass transition temperatures - Nylon-6 - Prepolymers - Stress-strain behaviors - Structure and properties;
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摘要
Amino-terminal nylon-6 prepolymer with average molecular weight about 1000 (PA1000) and isocyanate-terminal polyether prepolymer (OPU) were synthesized respectively, and then the thermoplastic elastomer (TPE) based on nylon-6 was synthesized with the reaction between PA1000 and OPU in dimethyl acetamide (DMAC). The structure and properties of the synthesized TPE were studied by FT-IR, WAXD, DSC, TG, POM, stress-strain curves and dissolved test. The results show that the synthesized TPE exhibits a similar stress-strain behavior as crosslinked rubber, and has a high tensile strength and high elongation at break. TPE can be possessed of both high melt temperature (>170°C) and low glass transition temperature (
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页码:100 / 104
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