High-performance multi-functional graphene/hexagonal boron nitride/poly(ethylene oxide) nanocomposites through enhanced interfacial interaction by coordination

被引:3
作者
Lin, Chen [1 ]
Ye, Xiong-Ying [2 ]
Xie, Xu-Ming [1 ]
机构
[1] Tsinghua Univ, Dept Chem Engn, Lab Adv Mat MOE, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Dept Precis Instrument, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
GRAPHENE OXIDE; THERMAL-CONDUCTIVITY; ORGANIC-SOLVENTS; MECHANICAL-PROPERTIES; NITRIDE NANOSHEETS; COMPOSITES; SOLUBILITY; REDUCTION; TRANSPORT; HYDROGELS;
D O I
10.1039/c8ra06325g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, multi-functional nanocomposites with excellent mechanical, electrical and thermal properties were prepared through metal-ion coordination. Reduced graphene oxide (rGO) and hexagonal boron nitride (h-BN) interacted through calcium coordination bonding. Poly(ethylene oxide) (PEO) was added to bridge these two nanomaterials, providing more resistance to tensile deformation. The results of UV-Vis and FTIR spectra proved that coordination bonding was successfully formed among the three compounds. SEM images showed homogenous dispersions of the nanocomposite. After calcium-ion coordination, the mechanical, electrical and thermal properties of Ca2+-coordinated rGO/BN/PEO composite improved significantly, indicating that metal-ion coordination is a potential method for multi-functional nanocomposite fabrication.
引用
收藏
页码:36761 / 36768
页数:8
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