New Crystal Structures of Rare-Earth Metal(III) Oxotellurates(IV) RE2Te3O9: A1-Type (RE=La, Ce) and A2-Type (RE=Pr, Nd)

被引：2

作者：

Chou, Sheng-Chun ^{[1
]}

Höss, Patrick ^{[1
]}

Russ, Philip L. ^{[1
]}

Strobel, Sabine ^{[1
]}

Schleid, Thomas ^{[1
]}

机构：

[1] Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart

来源：

Zeitschrift fur Anorganische und Allgemeine Chemie | 2021年 / 647卷 / 2-3期

关键词：

Cerium; Crystal structure; Lanthanum; Neodymium; Oxotellurates(IV); Praseodymium; Stereochemical lone-pair activity;

D O I：

10.1002/zaac.202000385

中图分类号：

学科分类号：

摘要：

The new rare-earth metal(III) oxotellurates(IV) RE2Te3O9 (RE=La−Nd) of the so far unknown A-type structure can be obtained as needle-shaped single crystals through solid-state reactions of the corresponding binary oxides. Their crystal structures were determined as A1-type for RE=La and Ce or A2-type for RE=Pr and Nd by single-crystal X-ray diffraction. Both structure types crystallize in the monoclinic crystal system, but in two different non-centrosymmetric space groups: the A1-type with Z=8 in space group P21 (La2Te3O9: a=569.54(3), b=2230.12(13), c=1464.71(4) pm, β=101.205(3)°; Ce2Te3O9: a=567.02(3), b=2222.61(13), c=1457.13(9) pm, β=101.134(3)°) or the A2-type with Z=16 in space group Cc (Pr2Te3O9: a=2838.61(16), b=563.89(3), c=2522.08(15) pm, β=118.816(3)°; Nd2Te3O9: a=2826.38(16), b=561.47(3), c=2511.94(15) pm, β=118.841(3)°). In spite of the differences in the unit-cell parameters and the symmetry, both structures consist of quite similar fundamental building blocks (FBBs) consisting of eight crystallographically distinct rare-earth metal-oxygen polyhedra with C.N.(RE3+) from seven to nine and always twelve different ψ1-tetrahedral oxotellurate(IV) anions [TeO3]2−, which show a high number of secondary bonding interactions (SBIs) with each other in all four cases. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH.

引用

页码：134 / 150

页数：16

共 65 条

[1]

Nikiforov G.B., Kusainova A.M., Berdonosov P.S., Dolgikh V.A., Lightfoot P., J. Solid State Chem., 146, pp. 473-477, (1999)

[2]

Lindqvist O., Acta Chem. Scand., 22, pp. 977-982, (1968)

[3]

Beyer H., Z. Kristallogr., 124, pp. 228-237, (1967)

[4]

Worlton T.G., Beyerlein R.A., Phys. Rev., B 12, pp. 1899-1907, (1975)

[5]

Hanke K., Naturwissenschaften, 54, (1967)

[6]

Walitzi E.M., Tschermaks Mineral. Petrogr. Mitt., 10, pp. 241-255, (1965)

[7]

Zemann J., Monatsh. Chem., 102, pp. 1209-1216, (1971)

[8]

Dolgikh V.A., Russ. J. Inorg. Chem., 36, pp. 1117-1123, (1991)

[9]

Marukhnov A.V., Pushkin D.V., Serezhkin V.N., Russ. J. Inorg. Chem., 52, pp. 203-208, (2007)

[10]

Wickleder M.S., Chem. Rev., 102, pp. 2011-2087, (2002)

← 1 2 3 4 5 6 7 →