Gradient Membrane Electrode of Proton Exchange Membrane Fuel Cell

被引:0
|
作者
Zheng J. [1 ,2 ]
Dai N. [1 ]
Wang Q. [1 ]
Zhu S. [3 ]
Zheng J. [1 ,2 ]
机构
[1] School of Automotive Studies, Tongji University, Shanghai
[2] Clean Energy Automotive Engineering Center, Tongji University, Shanghai
[3] State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai
[4] Department of Electrical and Computer Engineering, Florida State University, 32310, FL
关键词
Buckypaper; Fuel cell; Gradient distribution; Membrane electrode;
D O I
10.11908/j.issn.0253-374x.2018.s1.039
中图分类号
学科分类号
摘要
Starting from the preparation of fuel cell catalysts and catalytic layers with low cost, high durability and high utilization ratio of catalytic active sites, the surface modification of carbon nanotubes (CNTs) was carried out by using different oxidants and operation modes. Then, Pt/CNTs catalysts were prepared by the chemical reduction of polyols. Finally, a new type of catalytic layer with buckypaper structure and gradient distribution of catalytic active center and porosity was proposed. The catalytic layer can promote the mass transfer and electronic conductivity of fuel cells, which improving the utilization of platinum. © 2018, Editorial Department of Journal of Tongji University. All right reserved.
引用
收藏
页码:228 / 236
页数:8
相关论文
共 10 条
  • [1] Yi B., Principle of Fuel Cell-technology-application, (2003)
  • [2] Andersen S.M., Borghei M., Lund P., Et al., Durability of carbon nanofiber (CNF) & carbon nanotube (CNT) as catalyst support for proton exchange membrane fuel cells, Solid State Ionics, 231, (2013)
  • [3] Chen W., Xin Q., Sun G., Aging of precious metal catalysts for low temperature fuel cells, Journal of Catalysis, 29, 5, (2008)
  • [4] Marinoiu A., Teodorescu C., Carcadea E., Et al., Graphene-based materials used as the catalyst support for PEMFC applications, Materials Today: Proceedings, 2, 6, (2015)
  • [5] Yan C., Study on fuel cell catalyst supported by carbon nanotubes, (2008)
  • [6] Sekol R.C., Li X., Cohen P., Et al., Silver palladium core-shell electrocatalyst supported on MWNTs for ORR in alkaline media, Applied Catalysis B: Environmental, 138, (2013)
  • [7] Jafri R.I., Sujatha N., Rajalakshmi N., Et al., Au-MnO<sub>2</sub>/MWNT and Au-ZnO/MWNT as oxygen reduction reaction electrocatalyst for polymer electrolyte membrane fuel cell, International Journal of Hydrogen Energy, 34, 15, (2009)
  • [8] Su H.N., Zeng Q., Liao S.J., Et al., High performance membrane electrode assembly with ultra-low platinum loading prepared by a novel multi catalyst layer technique, International Journal of Hydrogen Energy, 35, 19, (2010)
  • [9] Wang D., Xin H.L., Hovden R., Et al., Structurally ordered intermetallic platinum-cobalt core-shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts, Nature Materials, 12, 1, (2013)
  • [10] Wang X., Study on membrane electrode structure of proton exchange membrane fuel cell, (2006)