The advance in thermal property enhancement mechanism of polymer/POSS nanocomposites

被引：0
|
作者：
Xu, Hong-Yao [1 ,2 ]
Jia, Yong [2 ]
Feng, Yan [2 ]
机构：
[1] State Key Laboratory for Modification of Chemical Fibers and Polymeric Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
[2] School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China
来源：
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2008年 / 24卷 / 12期
关键词：
Thermodynamic properties - Hybrid materials - Silica;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Polyhedral oligosilsesquioixanes (POSS) consists of a new well-defined nanoscale molecule (0.5~3 nm in size) with an inorganic silica-like core ((SiO1.5)n) surrounded by eight organic corner group (functional or inert) which possess high thermal stability. Polymer/POSS nanocomposites have attracted great interest of many researchers recently due to their excellent thermal properties relative to polymeric materials. In this paper, the influence factors such as dipolar-dipolar effect, hydrogen interaction, nanometer enhancement effect, dilute and free volume effect, on the thermal property of polymer/ POSS nanocomposites were summarized and different thermal property enhancement mechanisms were discussed.
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页码：15 / 19
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