Optimization of Microstructure and Photoelectric Properties of Perovskite Thin Films

被引：1

作者：

Guo X.-B. ^{[1
]}

Yu W. ^{[1
]}

Li J. ^{[1
]}

Jiang Z.-Y. ^{[2
]}

机构：

[1] College of Physics Science and Technology, Hebei University, Baoding, 071002, Hebei

[2] School of Physics and Nuclear Energy Engineering, Beihang University, Beijing

来源：

Guangzi Xuebao/Acta Photonica Sinica | 2017年 / 46卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Perovskite; Photoelectric properties; Solar cells; Solvent annealing; Thin film morphology;

D O I：

10.3788/gzxb20174603.0331004

中图分类号：

学科分类号：

摘要：

Using the pure N, N-dimethyl formamide, pure dimethyl sulfoxide and mixed solvents with different proportion as precursor solvent, respectively, the perovskite thin film samples were prepared. The samples were divided as two sets, one set was processed by thermal annealing in N2 atmosphere, while the other set was processed by solvent annealing in dimethyl sulfoxide vapor atmosphere. The microstructure and optoelectronic properties of the samples were systematically analyzed. The results show that, compared with the thermal annealing, the grain size and uniformity of samples can be significantly improved by solvent annealing, which reduces volume fraction of grain boundaries or interfaces in the films. By solvent annealing and mixed solvents, the absorption and utilization ratio of visible light are enhanced, the morphology is improved, and the crystallization quality is optimized. The increasing of photoluminescence intensity indicates that the defect densities of thin film are reduced. Thin film solar cells were fabricated using the optimized perovskite film as the absorber layer, and a conversion efficiency of 15.7% was achieved. © 2017, Science Press. All right reserved.

引用

共 25 条

[21]

Chen Q., Zhou H., Hong Z., Et al., Planar heterojunction perovskite solar cells via vapor-assisted solution process, Journal of the American Chemical Society, 136, 2, pp. 622-625, (2014)

[22]

Liu M., Johnston M.B., Snaith H.J., Efficient planar heterojunction perovskite solar cells by vapour deposition, Nature, 501, 7467, pp. 395-398, (2013)

[23]

Zhao L., Luo D., Wu J., Et al., High-performance inverted planar heterojunction perovskite solar cells based on lead acetate precursor with efficiency exceeding 18%, Advanced Functional Materials, 26, 20, pp. 3508-3514, (2016)

[24]

Ikhmayies S.J., Ahmadbitar R.N., An investigation of the bandgap and Urbach tail of spray-deposited SnO2: F thin films, Physica Scripta, 84, 5, pp. 143-146, (2011)

[25]

Im J.H., Jang I.H., Pellet N., Et al., Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells, Nature Nanotechnology, 9, 11, pp. 927-932, (2014)

← 1 2 3 →