Synthesis and Structure of Gold(III) Compounds with i-Pr- and t-Bu-Substituted Tetraarylporphyrins

被引：0
|
作者：
Bardina, E. E. [1 ]
Makotchenko, E. V. [1 ]
Birin, K. P. [2 ]
Shremzer, E. S. [2 ]
Abramov, P. A. [1 ]
Gorbunova, Yu. G. [2 ,3 ]
Gushchin, A. L. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow, Russia
[3] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 08期
关键词：
gold; tetraarylporphyrins; complexes; synthesis; X-ray diffraction analysis; cyclic voltammetry; non-covalent interactions; PORPHYRIN COMPLEXES; GOLD; PYRAZINOPORPHYRINS; EFFICIENT;
D O I：
10.1134/S1070328424600591
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Gold(III) compounds with tetrakis(4-tert-butylphenyl)porphyrin, [Au(TTBPP)][AuCl4] (I), and with tetrakis(4-isopropylphenyl)porphyrin, [Au(TIPPP)][AuCl4] (II), were synthesized for the first time. The obtained compounds were characterized by elemental analysis, H-1 NMR spectroscopy, cyclic voltammetry, and X-ray diffraction analysis of solvated complexes (CCDC no. 2333206 (Ia) and 2333207 (IIa)). Study of the structures of the obtained gold(III) complexes confirmed their specific character consisting in the formation of additional Au center dot center dot center dot Au and Au center dot center dot center dot Cl contacts between neighboring complexes giving weak intermolecular bonds.
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页码：579 / 586
页数：8
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