Advances in Primary Amine Synthesis by Reductive Amination of Alcohols Using Heterogeneous Metal Catalysts

被引：0
|
作者：
Liu Y.-X. [1 ]
Shu H.-M. [1 ]
Liu H.-Y. [2 ]
Liu X.-S. [1 ]
Zeng M. [1 ]
Zhou K. [1 ]
Wei Z.-J. [2 ]
机构：
[1] Research and Development Base of Catalytic Hydrogenation, College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou
[2] Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou
来源：
Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2018年 / 32卷 / 03期
关键词：
Alcohols; Heterogeneous catalyst; Primary amine; Reductive amination;
D O I：
10.3969/j.issn.1003-9015.2018.03.001
中图分类号：
学科分类号：
摘要：
Application of heterogeneous metal catalysts in the synthesis of primary amines via reductive amination of alcohols and NH3 is reviewed. Reaction mechanism of alcohol amination (including condensation amination and reductive amination) and catalytic systems used for reductive amination are summarized. Alcohol dehydrogenation is the rate-limiting step in reductive amination of alcohols and NH3. In addition, metal dehydrogenation activity varies due to their different adsorption capacities for NH3 and amines. Furthermore, this review gives an overview of primary amine synthesis, including the development of heterogeneous catalysts for reductive amination of alcohols and NH3 by hydrogen-autotransfer amination without hydrogen, employment of suitable supports and synthesis technology of primary amine compounds from biomass-based alcohols. © 2018, Editorial Board of Journal of Chemical Engineering of Chinese Universities". All right reserved."
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页码：487 / 498
页数：11
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