Sepiolite fiber reinforced TiO2/SiO2 composite aerogel based on CTAB "template" effect

被引:2
作者
Shang, Zexin [1 ]
Lei, E. [1 ,2 ]
Chen, Yanan [1 ,2 ]
Zhao, Dan [1 ,2 ]
Wei, Yu [1 ]
Chai, Qian [1 ]
Wei, Hao [1 ]
Zhao, Yaoyu [1 ]
机构
[1] Tianjin Chengjian Univ, Sch Mat Sci & Engn, Tianjin 300384, Peoples R China
[2] Tianjin Chengjian Univ, Tianjin Key Lab Bldg Green Funct Mat, Tianjin 300384, Peoples R China
关键词
PHOTOCATALYTIC DEGRADATION; SILICA AEROGELS; TIO2; CATALYST;
D O I
10.1007/s10854-024-13564-7
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
TiO2/SiO2 composite aerogel was prepared by sol-gel method with atmospheric pressure drying. However, the aerogel suffered from poor structural strength, and in most cases, they lost their shape under thermal stress. Herein, a novel strategy that improved the structure chunkiness and photocatalytic activity of aerogel was proposed. The formation process of sepiolite fiber-reinforced TiO2/SiO2 composite aerogel explored effect of hexadecyl trimethyl ammonium bromide (CTAB) as a "template" on the physicochemical properties of aerogel and the toughened mechanism of sepiolite fiber in gel network. The synergistic effect of CTAB, sepiolite fiber and TiO2/SiO2 composite aerogel is conducive to optimizing the structure of aerogel and improving the photocatalytic degradation efficiency. The results showed that sepiolite fiber-reinforced TiO2/SiO2 composite aerogel not only had good chunk formation, but also enhanced the photocatalytic activity of rhodamine B (Rh B) solution by three times under ultraviolet (UV) irradiation.
引用
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页数:12
相关论文
共 35 条
[1]   Enhanced Photocatalytic Activity of CuWO4 Doped TiO2 Photocatalyst Towards Carbamazepine Removal under UV Irradiation [J].
Anucha, Chukwuka Bethel ;
Altin, Ilknur ;
Bacaksiz, Emin ;
Kucukomeroglu, Tayfur ;
Belay, Masho Hilawie ;
Stathopoulos, Vassilis N. .
SEPARATIONS, 2021, 8 (03) :1-23
[2]   Core shell Fe3O4@TiO2/silica aerogel nanocomposite; synthesis and study of structural, magnetic and photocatalytic properties [J].
Ardani, Mina ;
Imani, Mina ;
Tadjarodi, Azadeh .
MICROPOROUS AND MESOPOROUS MATERIALS, 2022, 338
[3]   Silica-coated nanocrystalline TiO2 with improved thermal stability [J].
Bedilo, Alexander F. ;
Shuvarakova, Ekaterina I. ;
Volodin, Alexander M. .
CERAMICS INTERNATIONAL, 2019, 45 (03) :3547-3553
[4]   Carbon Dot-Modified TiO2@SiO2 Aerogel as an Anode for Lithium-Ion Batteries [J].
Chen, Zanyu ;
Hu, Jiugang ;
Ding, Kuixing ;
Tan, Jun ;
Hou, Hongshuai ;
Ji, Xiaobo .
NANOMANUFACTURING AND METROLOGY, 2023, 6 (01)
[5]   SiO2/TiO2 composite aerogels: Preparation via ambient pressure drying and photocatalytic performance [J].
Cheng, Shengjun ;
Liu, Xinling ;
Yun, Shan ;
Luo, Hongjie ;
Gao, Yanfeng .
CERAMICS INTERNATIONAL, 2014, 40 (09) :13781-13786
[6]   CTAB modified TiO2 supported on HZSM-5 zeolite for enhanced photocatalytic degradation of azophloxine [J].
Dong, Yinghao ;
Zhang, Wenjie ;
Tao, Yingjie .
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2020, 9 (04) :9403-9411
[7]   Improvement of catalyst durability by deposition of Rh on TiO2 in photooxidation of aromatic compounds [J].
Einaga, H ;
Ibusuki, T ;
Futamura, S .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (01) :285-289
[8]   Synthesis and structural characteristics of high surface area TiO2 aerogels by ultrasonic-assisted sol-gel method [J].
Feng Qingge ;
Cai Huidong ;
Lin Haiying ;
Qin Siying ;
Liu Zheng ;
Ma Dachao ;
Ye Yuyang .
NANOTECHNOLOGY, 2018, 29 (07)
[9]   Sepiolite organic modifiers effect on pet/sepiolite nanocomposites degradation [J].
Fernandez-Menendez, T. ;
Garcia-Lopez, D. ;
Arguelles, A. ;
Fernandez, A. ;
Vina, J. .
POLYMER TESTING, 2022, 115
[10]   Development and Upscaling of SiO2@TiO2 Core-Shell Nanoparticles for Methylene Blue Removal [J].
Gomes, Barbara R. ;
Lopes, Joana L. ;
Coelho, Lorena ;
Ligonzo, Mattia ;
Rigoletto, Monica ;
Magnacca, Giuliana ;
Deganello, Francesca .
NANOMATERIALS, 2023, 13 (16)