Surface Structure of Acrylate Polymer Adhesives

被引：0
|
作者：
Roy S. [1 ]
Freiberg S. [2 ]
Leblanc C. [2 ]
Hore D.K. [1 ]
机构：
[1] Department of Chemistry, University of Victoria, Victoria, V8W 3V6, BC
[2] Mapei Inc., 2900 Avenue Francis-Hughes, Laval, H7L 3J5, QC
来源：
Langmuir | 2017年 / 33卷 / 08期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Acrylate polymers - Hetero-spectral correlation - Hydrogen bonding interactions - Polybutyl acrylate - Pressure sensitive adhesives - Spectral response - Sum-frequency spectroscopies - Total internal reflections;
D O I：
10.1021/acs.langmuir.6b03875
中图分类号：
学科分类号：
摘要：
Total internal reflection infrared (IR) absorption and visible-IR sum-frequency spectroscopies were used to study the role of acrylic acid in the evolution of surface structure in a poly(butyl acrylate)-based pressure-sensitive adhesive during the drying process. By monitoring these spectral responses and calculating the heterospectral correlation coefficients, we established that acrylic acid alters the nature of the molecular interactions at the surface. In the absence of acrylic acid, butyl acrylate orientation is driven by the packing of the polymer as the water evaporates. When acrylic acid is present, a rapid ordering of the copolymer takes place as a result of favorable hydrogen-bonding interactions with the surface. © 2017 American Chemical Society.
引用
收藏
页码：1763 / 1768
页数：5
相关论文
共 50 条
  • [31] POLYMER ADHESIVES IN USSR .2. CONSUMPTION OF ADHESIVES
    RAEVSKY, VG
    ADHESIVES AGE, 1976, 19 (03): : 23 - 29
  • [32] Surface effect on phase separation in a polyester urethane acrylate ter-polymer
    Han, HZY
    Lee, SS
    Manson, JAE
    Hilborn, JG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U157 - U157
  • [33] Enhancing electrical strength of acrylate polymer by using fluorinated monomer as surface modifier
    Wang, Chao
    Guo, Jia
    Li, Wen-Dong
    Li, Xiao-Ran
    Jiang, Zhi-Hui
    Guo, Bao-Hong
    Zhang, Guan-Jun
    MATERIALS LETTERS, 2019, 249 : 17 - 20
  • [34] THE HETEROGENEOUS STRUCTURE OF INTERPENETRATING POLYMER NETWORKS MADE OF OLIGOESTER ACRYLATE AND CO-POLYMER OF STYRENE WITH DIVINYLBENZENE
    LIPATOVA, TE
    SHEVCHUK, YS
    SHILOV, VV
    BOGDANOVICH, VA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1981, 23 (01): : 73 - 82
  • [35] Surface molecular aggregation structure and surface properties of poly (fluoroalkyl acrylate) thin films
    Honda, Koji
    Morita, Masamichi
    Takahara, Atsushi
    KOBUNSHI RONBUNSHU, 2007, 64 (04) : 181 - 190
  • [36] A ctivities of polymer materials for adhesives
    Sugizaki, Toshio
    Kobunshi, 2016, 65 (10) : 564 - 566
  • [37] BIOADHESION WITH POLYMER AND PROTEIN ADHESIVES
    WANG, PY
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 16 - INE
  • [38] Adhesives: Polymer Chemistry at Work
    Arz, Christof
    Dolomann, Andreas
    Meincke, Olaf
    Schulthess, Adrian
    Schwotzer, Willi
    CHIMIA, 2008, 62 (10) : 826 - 831
  • [39] POLYMER EMULSION BLENDS AS ADHESIVES
    不详
    TAPPI JOURNAL, 1987, 70 (09): : 155 - 155
  • [40] Structure and Properties of Fluorinated Acrylate Polymer Microspheres Filled Epoxy Resin Coatings
    Gao K.
    Xiang Y.
    Fang J.
    Ren Q.
    Wang C.
    Li J.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2023, 39 (08): : 66 - 73
12345