Recent Progress in Synthesis of Insensitive Energetic Compounds

被引：0

作者：

Huo H. ^{[1
]}

Xuan C.-L. ^{[1
]}

Bi F.-Q. ^{[1
]}

Zhang J.-R. ^{[1
]}

Zhou C. ^{[1
]}

Wang B.-Z. ^{[1
]}

机构：

[1] Xi'an Modern Chemistry Research Institute, Xi'an

来源：

Huozhayao Xuebao/Chinese Journal of Explosives and Propellants | 2019年 / 42卷 / 01期

关键词：

FOX-12; FOX-7; HATO; Insensitive ammunition; Insensitive energetic compounds; LLM-105; Organic chemistry;

D O I：

10.14077/j.issn.1007-7812.2019.01.002

中图分类号：

学科分类号：

摘要：

The research progresses in syntheses and properties (melting point, thermal decomposition temperature, density, enthalpy of formation, impact sensitivity, detonation velocity and detonation pressure, etc.) of 26 kinds of insensitive energetic compounds with excellent comprehensive properties reported in recent 10 years at home and abroad were reviewed, including 6 kinds of insensitive energetic compounds with intramolecular hydrogen bond, such as FOX-7, LLM-105, etc., 3 kinds of insensitive energetic compounds with intramolecular internal salt, such as TACOT, TNPCOT, etc.,4 kinds of insensitive energetic compounds with aza-aromatic ring, such as MTNI, DAAF, etc., and 13 kinds of insensitive energetic compounds with energetic ionic salts, such as HATO, FOX-12, etc. It is pointed out that insensitive energetic ionic salts are a kind of insensitive energetic compounds that having broad application aspects. The key development direction of insensitive energetic compounds are to strengthen the studies on molecular structure- properties relationship and basic application property, and to develop the convenient, efficient and green synthesis methods. 49 references were attached. © 2019, Editorial Board of Journal of Explosives & Propellants. All right reserved.

引用

页码：6 / 16

页数：10

共 49 条

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