Development of solution measurement using laser-induced breakdown spectroscopy integrated with micro-droplet ejection system

被引:1
作者
Ikezawa, Satoshi [1 ,2 ]
Wakamatsu, Muneaki [1 ,2 ]
Ueda, Toshitsugu [1 ,2 ]
机构
[1] Graduate School of IPS, Waseda University, Fukuoka-ken 808-0135
[2] Graduate School of IPS, Waseda University
关键词
LIBS; Micro-droplet; Quantitative analysis; Real time measurement;
D O I
10.1541/ieejsmas.127.343
中图分类号
学科分类号
摘要
The laser-induced breakdown spectroscopy (LIBS) using micro-droplet sodium chloride solution is presented. Since the 1980s, many liquid miniaturizations of analytical technique for LIBS measurements were reported. The method we present allowed micronizing the sample in such a way that whole volume of a sample was confined in the laser beam spot area (minimum beam spot diameter 53.2μm, microdroplet diameter 50-60μm) and was separated from its surrounding condition. If the sample's physical state was liquid, the density of solution could be controlled as needed. In this paper, originally designed ink-jet system for sampling procedure was presented. According to the new method, improved sensitivity for drawing calibration curves with the aim of the LIBS quantitative measurement were obtained.
引用
收藏
页码:343 / 346+2
相关论文
共 8 条
[1]  
Archontaki H.A., Crouch S.R., Evaluation of an Isolated Droplet Sample Introduction System for Laser-Induced Breakdown Spectroscopy, Applied Spectroscopy, 42, 5, pp. 741-746, (1988)
[2]  
Janzen C., Et al., Analysis of small droplets with a new detector for liquid chromatography based on laser-induced breakdown spectroscopy, Spectrochimica Acta Part B, 60, pp. 993-1001, (2005)
[3]  
Kumar A., Yueh F.Y., Miller T., Singh J.P., Detection of trace elements in liquids by laser-induced breakdown spectroscopy with a Meinhard nebulizer, Applied Optics, 42, 30, pp. 6040-6046, (2003)
[4]  
Xu L., Bulatov V., Gridin V.V., Schechter I., Absolute Analysis of Particulate Materials by Laser-Induced Breakdown Spectroscopy, Analytical Chemistry, 69, 11, pp. 2103-2108, (1997)
[5]  
Nakamura S., Ito Y., Sone K., Hiraga H., Kaneko K., Determination of an Iron Suspension in Water by Laser-Induced Breakdown Spectroscopy with Two Sequential Laser Pulses, Analytical Chemistry, 68, 17, pp. 2981-2986, (1996)
[6]  
Wakamatsu M., Ueda T., Particle Measurement Using LIBS, SICE Annual conference, pp. 3717-3720, (2005)
[7]  
Andreev A., Ueda T., Simulation of laser plasma emission characteristics of small solid particles in different gas atmospheres at various pressures, Trans. IEE J, 121-E, 11, pp. 593-598, (2001)
[8]  
Takeuchi Y., Nishi S., Features of Shear Mode Piezo Inkjet Head, Journal of the Imaging Society of Japan, 43, 6, pp. 509-514, (2004)