Fe2P2O7(H2O)2

被引：11

作者：

Giesber, Henry G. ^{[1
]}

Korzenski, Michael B. ^{[2
]}

Pennington, William T. ^{[1
]}

Kolis, Joseph W. ^{[1
]}

机构：

[1] Department of Chemistry, Clemson University, Clemson,SC,29634-1905, United States

[2] Laboratoire Crismat-ISMRA, 6 Boulevard du Marechal Juin, Caen Cedex,14050, France

来源：

Acta Crystallographica Section C: Crystal Structure Communications | 2000年 / 56卷 / 04期

关键词：

Crystalline materials - Titanium oxides;

D O I：

10.1107/S0108270199014407

中图分类号：

学科分类号：

摘要：

The compound diiron diphosphate dehydrate was synthesized hydrothermally. The remaining octahedral site of each iron is occupied by coordinated water. The H atoms of the water molecules all point into a common channel. The remaining H atoms have no obvious interactions. The synthesis of this compound requires titanium oxide (TiO) to be present although it does not become incorporated into the compound, as confirmed by EDAX. The reaction was heated for 3 D at 648 K and cooled in air to room temperature. Upon visual inspection of the quartz tube, the only crystalline material present were colorless truncated diamond-shaped crystals of the title compound and black polyhedral-shaped crystals precipitated from a clear solution.

引用

页码：399 / 400