Recent advances in thermodynamic modelling of ionic liquid solutions

被引：0
作者：
Li C. [1 ,2 ,3 ]
机构：
[1] State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing
[2] College of Chemical Engineering, Beijing University of Chemical Technology, Beijing
[3] Beijing Key Laboratory of Energy Environmental Catalysis, Beijing University of Chemical Technology, Beijing
来源：
Huagong Xuebao/CIESC Journal | 2020年 / 71卷 / 01期
关键词：
Activity coefficient; Electrostatic interaction; Equation of state; Hydrogen bond; Phase equilibria; Thermodynamics;
D O I：
10.11949/0438-1157.20191184
中图分类号：
学科分类号：
摘要：
Ionic liquids (ILs) is a novel and green solvent, and shows prospective applications in ILs related reaction and separation processes. Their thermodynamic properties and fluid phase equilibria data are instrumental for the ILs-related process design. This paper reviewed the recent advances in thermodynamic modelling of ILs solutions in terms of the following aspects, viz. study methods of solution thermodynamics, construction of solution thermodynamic models, the structure and intermolecular forces of ILs, thermodynamic models of ILs solution and their applications in fluid phase equilibria. Special focuse was given to the development of equation of state and excess Gibbs free energy or activity coefficient models, electrolyte and non-electrolyte solution models, as well as their treatment for Ils' structure, hydrogen bonding and electrostatic interactions. The merits and demerits of these models were analyzed, and some suggestions were proposed for the study of molecular thermodynamic models of Ils solutions. © All Right Reserved.
引用
收藏
页码：81 / 91
页数：10
相关论文
共 77 条
  • [21] Wang J., Li C., Shen C., Et al., Towards understanding the electrostatic interaction on the density of ionic liquids, Fluid Phase Equilibria, 279, 2, pp. 87-91, (2009)
  • [22] Glasser L., Lattice and phase transition thermodynamics of ionic liquids, Thermochimica Acta, 421, pp. 87-93, (2004)
  • [23] Binnemans K., Ionic liquid crystals, Chem. Rev., 105, pp. 4148-4204, (2005)
  • [24] Tohru I., Haruka Y., Micelle formation of nonionic surfactants in a room temperature ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate: surfactant chain length dependence of the critical micelle concentration, J. Colloid Interface Science, 356, 2, pp. 798-802, (2011)
  • [25] Lee A.A., Vella D., Perkin S., Et al., Are room-temperature ionic liquids dilute electrolytes?, J. Phys. Chem. Lett., 6, pp. 159-163, (2015)
  • [26] Tokuda H., Tsuzuki S., Susan A.B.H., Et al., How ionic are room-temperature ionic liquids? An indicator of the physicochemical properties, J. Phys. Chem. B, 110, pp. 19593-19600, (2006)
  • [27] Lee B.S., Lin S.T., A priori prediction of dissociation phenomena and phase behaviors of ionic liquids, Ind. Eng. Chem. Res., 54, pp. 9005-9012, (2015)
  • [28] Jiang S., Pitzer K.S., Phase equilibria and volumetric properties of aqueous CaCl<sub>2</sub> by an equation of state, AIChE Journal, 42, 2, pp. 585-594, (1996)
  • [29] Dong K., Zhang S., Wang Q., A new class of ion-ion interaction: Z-bond, Science China-Chemistry, 58, 3, pp. 495-500, (2015)
  • [30] Jiang W., Wang Y., Voth G.A., Molecular dynamics simulation of nanostructural organization in ionic liquid/water mixtures, J. Phys. Chem. B, 111, pp. 4812-4818, (2007)
12345678