Progress on Flame Retardant Modification of Polybenzoxazines

被引：0

作者：

Wang J. ^{[1
,2
]}

Lu Z. ^{[1
,2
]}

Zhang Y. ^{[3
]}

Liu B. ^{[1
,2
]}

Zhang W. ^{[2
]}

Xu H. ^{[2
]}

Fang X. ^{[2
]}

Ding T. ^{[2
]}

机构：

[1] Institute of Functional Polymer Composites, Henan University, Kaifeng

[2] College of Chemistry and Chemical Engineering, Henan University, Kaifeng

[3] Zhengzhou Technical College, Zhengzhou

来源：

Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2018年 / 34卷 / 05期

关键词：

Benzoxazine; Flame retardant; Modification;

D O I：

10.16865/j.cnki.1000-7555.2018.05.031

中图分类号：

学科分类号：

摘要：

In recent years, benzoxazine resins have attracted increasing attention in academia and many industrial manufacturing industries due to good thermal, chemical, electrical and mechanical properties, in addition to their low melt viscosity, the addition of no catalyst and no small molecule released during the curing process. The benzoxazine monomer has six-element O, N-containing heterocyclic structure, and a compound with N-containing mesh structure similar as phenolic resin can be polymerized through ring-opening polymerization, which is hard to burn, however, the flame retardant property of traditional benzoxazine resin still can not meet application demand of high flame retardant field, which restricting their applications as matrices for some high-performance composites. Therefore, the flame-retarded modification and application of benzoxazine have aroused great interest. In this paper, the flame-retarded modification of benzoxazine resin in recent years were reviewed from the aspects of intrinsically flame-retarded modification, copolymerization modification and physical blending modification. Meanwhile, the application of benzoxazine as flame retardant synergist was summarized, and the flame retardant modification directions of benzoxazine were prospected. © 2018, Editorial Board of Polymer Materials Science & Engineering. All right reserved.

引用

页码：183 / 190

页数：7

共 39 条

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