Comparison of Two Phosphinidenes Binding to Silicon(IV)dichloride as well as to Silylene

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[1] Kundu, Subrata
[2] Sinhababu, Soumen
[3] Siddiqui, Mujahuddin M.
[4] Luebben, Anna V.
[5] Dittrich, Birger
[6] Yang, Tao
[7] Frenking, Gernot
[8] Roesky, Herbert W.
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Dittrich, Birger (birger.dittrich@uni-duesseldorf.de) | 2018年 / American Chemical Society卷 / 140期
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The cyclic alkyl(amino) carbene (cAAC) anchored silylene with two phosphinidenes was isolated as (cAAC)Si{P(cAAC)}2 (3) at room temperature, which was synthesized from the reduction of (Cl2)Si{P(cAAC)}2 (2) using 2 equiv of KC8. Compound 2 resulted from the reaction of 2 equiv of (cAAC)PK (1) with 1 equiv of SiCl4. Compounds 2 and 3 are the first examples where two terminal phosphinidenes are binding each to a silicon center characterized by single crystal X-ray structural analysis. Furthermore, the structure and bonding of compounds 2 and 3 have been investigated by theoretical methods for comparison. © Copyright 2018 American Chemical Society.
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