Synthesis, crystal structure and thermal property of 1-Amino-2, 4-dinitroimidazole

被引：0

作者：

Jing, Mei ^{[1
,2
]}

Shu, Yuan-Jie ^{[2
]}

Wang, Jun ^{[2
]}

Ma, Qing ^{[2
]}

Zhang, Xiao-Yu ^{[2
]}

Huang, Yi-Gang ^{[2
]}

机构：

[1] Department of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang

[2] Institute of Chemical Materials, CAEP, Mianyang

来源：

Hanneng Cailiao/Chinese Journal of Energetic Materials | 2014年 / 22卷 / 04期

关键词：

1-Amino-2; 4-dinitroimidazole; Energetic compound; Organic chemistry; Structure and property; Synthesis;

D O I：

10.3969/j.issn.1006-9941.2014.04.005

中图分类号：

学科分类号：

摘要：

1-Amino-2, 4-dinitroimidazole (ADNI) was synthesized by amination of 2, 4-dinitroimidazole with 2, 4, 6-trimethylbenzenesulfonic hydroxylamine (MSH) in a total yield of 57.8%. The structure of ADNI was characterized by IR, 1H NMR, LC-MS and single crystal X-ray diffraction. Results show that ADNI belongs to orthorhombic system, space group Pca21 with a=10.0626(14) Å, b=55.684(8) Å, c=11.5639(15) Å, Z=4, Dc=1.774 g·cm-3, and DSC test results reveal that ADNI has good thermal stability.

引用

页码：454 / 457

页数：3

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