Preparation of g-C3N4/TiO2 composites and the mechanism research of the photocatalysis degradation of ibuprofen

被引:0
作者
Su, Hai-Ying [1 ]
Wang, Ying-Fei [1 ]
Wang, Feng-Liang [1 ]
Su, Yue-Han [1 ]
Cai, Zong-Wei [1 ]
Liu, Guo-Guang [1 ]
Lü, Wen-Ying [1 ]
Yao, Kun [1 ]
Li, Fu-Hua [1 ]
Chen, Ping [1 ]
机构
[1] School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou,510006, China
来源
Zhongguo Huanjing Kexue/China Environmental Science | 2017年 / 37卷 / 01期
关键词
Transmission electron microscopy - Oxygen - Photocatalysis - Absorption spectroscopy - X ray diffraction;
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摘要
In this experiment, titanium trichloride was chosen as the titanium source of TiO2 and dicyandiamide was selected as the precursor of g-C3N4 to prepare the g-C3N4/TiO2 composites. The morphology, elements, and catalytic properties characterization of g-C3N4/TiO2 were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD) and ultraviolet-visible absorption spectrum(UV-vis). The results showed that TiO2 could be attached on the surface of g-C3N4 well. The doping ratio 1:9 of C3N4 and TiO2 showed the highest photocatalytic activity on the degradation of IBU due to the red-shift of the catalyst. The photocatalytic degradation of IBU followed pseudo-first-order kinetics. Acidity increased the photocatalytic degradation of IBU. The quenching experiment demonstrated that the contribution rate of ·OH was 73.7%, indicating that ·OH played a major role in the photocatalytic degradation of IBU. © 2017, Editorial Board of China Environmental Science. All right reserved.
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页码:195 / 202
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