Arene-perfluoroarene interaction: Properties, constructions, and applications in materials science

被引:8
作者
Zhang, Shu [1 ,2 ]
Chen, Aocheng [1 ,2 ]
An, Yi [1 ,2 ]
Li, Quan [1 ,2 ,3 ]
机构
[1] Southeast Univ, Inst Adv Mat, Nanjing 211189, Jiangsu, Peoples R China
[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
[3] Kent State Univ, Mat Sci Grad Program, Kent, OH 44242 USA
关键词
PI-PI INTERACTIONS; LIQUID-CRYSTAL; 1/1; COMPLEXES; NONCOVALENT INTERACTIONS; DENSITY FUNCTIONALS; PHASE; DISPERSION; STACKING; BENZENE; POLYMER;
D O I
10.1016/j.matt.2024.06.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Arene-perfluoroarene interaction is a unique form of p-p p interaction that has gained attention in recent years. This review begins by introducing the properties of arene-perfluoroarene interaction to highlight its significant difference from arene-arene interaction. Through employing density functional theory (DFT) calculations, we elucidate the binding affinities of diverse arene-perfluoroarene interaction pairs. Moreover, manifold self-assembly constructions arise from the varying binding affinities of arene-perfluoroarene interaction in solid and solution phases. The impact of arene-perfluoroarene interaction in materials science is significant, with numerous examples covering various popular categories of materials, such as graphenes, perovskites, and hydrogels, as well as functions, such as organic luminescent materials, solar cells, and biological engineering materials. This review is expected to offer guidance on the application of arene-perfluoroarene interaction in materials science, providing an alternative tool for current challenges in the field.
引用
收藏
页码:3317 / 3350
页数:34
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