Room temperature-based hydrogen gas sensing over Laser-Induced Graphene electrode supported Pt nanoparticles for low LOD

被引:4
作者
Lim, Minseob [1 ]
Kim, Jun Young [1 ]
Kang, Hyunji [1 ]
Yun, Tae Woong [1 ]
Cho, Hong-Baek [1 ]
Choa, Yong-Ho [1 ]
机构
[1] Hanyang Univ, Dept Mat Sci & Chem Engn, Ansan 15588, South Korea
关键词
Hydrogen detection; Chemiresistive sensor; Gas sensor; Graphene oxide; PERFORMANCE; OXIDE; DECORATION; CATALYSTS; PD;
D O I
10.1016/j.snr.2024.100247
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
This study introduces a novel hydrogen sensor that operates efficiently at room temperature with high sensitivity and selectivity. This sensor was created by utilizing a platinum on laser-induced graphene (Pt/LIG) structure. The synthesis process involves the creation of highly crystalline graphene with a large surface area, which serves as an optimal support for nanosized pt catalysts. Post-synthesized Pt nanoparticles were dispersed on the surface of the LIG electrode and envisaged for the hydrogen gas sensing property under ambient conditions without a heating or sensor device. Analysis showed that the Pt nanoparticles are uniquely characterized by their narrow size distribution of less than 5 nm and their homogeneous deposition on the LIG substrate, which itself exhibits a substantial specific surface area of 187.4 m2/g. This configuration enables the sensor to achieve a very low limit for detection of hydrogen to 200 ppb. Moreover, the sensor demonstrates exceptional performance attributes, including high sensitivity, excellent linearity, and remarkable cycle stability over 50 cycles. The synergy between the high surface area of the LIG and the catalytic activity of the Pt nanoparticles facilitates the detection of hydrogen at room temperature. This study contributes significantly to the field of gas sensing technology, particularly in applications requiring accurate and reliable hydrogen detection at ambient conditions.
引用
收藏
页数:7
相关论文
共 49 条
[1]   Fluence-Dependent Morphological Transitions in Laser-Induced Graphene Electrodes on Polyimide Substrates for Flexible Devices [J].
Abdulhafez, Moataz ;
Tomaraei, Golnaz N. ;
Bedewy, Mostafa .
ACS APPLIED NANO MATERIALS, 2021, 4 (03) :2973-2986
[2]   Response characteristics of a highly sensitive gas sensor using a titanium oxide nanotube film decorated with platinum nanoparticles [J].
Abe, Hiroyuki ;
Kimura, Yasuo ;
Ma, Teng ;
Tadaki, Daisuke ;
Hirano-Iwata, Ayumi ;
Niwano, Michio .
SENSORS AND ACTUATORS B-CHEMICAL, 2020, 321
[3]   Hydrogen sensor based on graphene/ZnO nanocomposite [J].
Anand, Kanika ;
Singh, Onkar ;
Singh, Manmeet Pal ;
Kaur, Jasmeet ;
Singh, Ravi Chand .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 195 :409-415
[4]   Stable and durable laser-induced graphene patterns embedded in polymer substrates [J].
Cao, Lijun ;
Zhu, Shuairu ;
Pan, Baohai ;
Dai, Xinyan ;
Zhao, Weiwei ;
Liu, Yuan ;
Xie, Weiping ;
Kuang, Yongbo ;
Liu, Xiaoqing .
CARBON, 2020, 163 :85-94
[5]   Laser-Induced Graphene Strain Sensors Produced by Ultraviolet Irradiation of Polyimide [J].
Carvalho, Alexandre F. ;
Fernandes, Antonio J. S. ;
Leitao, Catia ;
Deuermeier, Jonas ;
Marques, Ana C. ;
Martins, Rodrigo ;
Fortunato, Elvira ;
Costa, Florinda M. .
ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (52)
[6]   The effect of gas jets on the explosion dynamics of hydrogen-air mixtures [J].
Chang, Xinyu ;
Bai, Chunhua ;
Zhang, Bo .
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2022, 162 :384-394
[7]  
Choi SJ, 2018, ELECTRON MATER LETT, V14, P221
[8]   High-Performance Nanostructured Palladium-Based Hydrogen Sensors-Current Limitations and Strategies for Their Mitigation [J].
Darmadi, Iwan ;
Nugroho, Ferry Anggoro Ardy ;
Langhammer, Christoph .
ACS SENSORS, 2020, 5 (11) :3306-3327
[9]   The decoration of TiO2/reduced graphene oxide by Pd and Pt nanoparticles for hydrogen gas sensing [J].
Esfandiar, A. ;
Ghasemi, S. ;
Irajizad, A. ;
Akhavan, O. ;
Gholami, M. R. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (20) :15423-15432
[10]   Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications [J].
Georgakilas, Vasilios ;
Otyepka, Michal ;
Bourlinos, Athanasios B. ;
Chandra, Vimlesh ;
Kim, Namdong ;
Kemp, K. Christian ;
Hobza, Pavel ;
Zboril, Radek ;
Kim, Kwang S. .
CHEMICAL REVIEWS, 2012, 112 (11) :6156-6214