Aligned Macroporous Monoliths by Ice-Templating

被引：0
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作者：
Pan, Zheng-Ze [1 ]
Lv, Wei [2 ]
Yang, Quan-Hong [3 ,4 ]
Nishihara, Hirotomo [1 ,5 ]
机构：
[1] Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, 2-1-1 Katahira, Aoba-ku, Miyagi, Sendai,980-8577, Japan
[2] Shenzhen Geim Graphene Center, Engineering Laboratory for Functionalized Carbon Materials, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China
[3] Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, China
[4] Joint School of National University of Singapore, Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, China
[5] Institute of Multidisciplinary Research for Advance Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Miyagi, Sendai,980-8577, Japan
来源：
Bulletin of the Chemical Society of Japan | 2022年 / 95卷 / 04期
关键词：
Wei Lv received his Ph.D. degree from Tianjin University in 2012 under the supervision of Prof. Quan-Hong Yang; and now he is an associate professor at Tsinghua Shenzhen International Graduate School; Tsinghua University. His research interests focus on electrochemical energy storage devices and related materials; such as carbon-based hosts and catalysts in Li-S batteries and lithium metal anodes. He has been granted by the Excellent Young Scientists Fund of NSFC and the Guangdong Natural Science Funds for Distinguished Young Scholar; and identified as a Highly Cited Researcher by Clarivate (2020 and 2021).This work was supported by [!text type='JS']JS[!/text]PS Grant Number 17H01042; !text type='JS']JS[!/text]T CREST (JPMJCRI18R3); Association for Chemical Innovation; the Five-star Alliance in NJRC Mater. & Dev; !text type='JS']JS[!/text]T SICORP Grant no. JPM[!text type='JS']JS[!/text]C2112. We also would like to express thanks for the support from the National Key Research and Development Program of China (2018YFE0124500) and the Overseas Research Cooperation Fund of SIGS (HW2021002);
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摘要：
The ice-templating (IT) approach has become a popular way to prepare macroporous monoliths due to environmental friendliness and low cost, as well as the controllability of the macroporosity and exterior structures. In particular, a directional freezing process induces the formation of aligned icecrystals that afford a brand-new material genre: aligned macroporous monoliths (AMMs). This short review gives an overview of the IT technique and the preparation of AMMs, with a subsequent unfolding of two representative AMMs, i.e., aligned micro-honeycomb monoliths and aligned microlamellar monoliths. These AMMs are characterized with their structural anisotropy and regularity, which imparts potentials towards various applications. We particularly highlighted the utilization of these AMMs in the context of thermal insulation, filtration, energy storage and structural engineering. Finally, future directions within this research field are also discussed. © 2022 The Chemical Society of Japan.
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页码：611 / 620
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