Langmuir films cast from poly(dipropylsiloxane) on water-ethylene glycol subphases

被引:0
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作者
Belousov, S.I. [1 ]
Korochkin, D.I. [1 ]
Godovskij, Yu.K. [1 ]
机构
[1] Karpov Inst. of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 103064, Russia
关键词
Glycols - Silicones - Thin films - Water;
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摘要
The behavior of monomolecular and thin films of poly(dipropylsiloxane) spread on the subphases of ethylene glycol and its mixtures with water was studied by measuring surface pressure as a function of specific surface area per repeating monomer unit. It was shown that poly(dipropylsiloxane) forms stable monolayers on ethylene glycol. The mechanism describing the formation of layers on the alcohol subphase was advanced. For a series of polymers, poly(dimethylsiloxane)-poly(diethylsiloxane)- poly(dipropylsiloxane), the structure and properties of monomolecular films were compared.
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页码:1450 / 1454
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