Complex creep phenomenon in Zr 55 Cu 30 Ni 5 Al 10 metallic glass

被引:0
作者
Yamazaki Y. [1 ]
Takami E. [1 ]
Hamasaki R. [1 ]
机构
[1] National Institute of Technology, Ube College, Department of Mechanical Engineering, Tokiwadai, Ube
基金
日本学术振兴会;
关键词
Amorphous alloy; Creep; Glass transition; Metallic glass;
D O I
10.2472/jsms.68.218
中图分类号
学科分类号
摘要
Metallic glass has both metallic (high electrical conductivity) and glassy (thermoplasticity) properties. Therefore, metallic glass is expected to be used in various applications such as precision processing products requiring metallic properties. It is implicitly considered that the mechanical creep is expressed in glassy materials as a result of transition from a glass state to a supercooled liquid state due to thermal glass transition. However, the relationship between thermal glass transition and mechanical creep has not been investigated in detail so far. In this study, creep behaviors were measured by thermomechanical analysis (TMA) in Zr55Cu30Ni5Al10 metallic glass, which is a typical alloy system, to obtain creep onset temperatures under various applied tensile stresses and heating rates. As a result, at applied tensile stress of 5 MPa, the creep onset temperature monotonously increased with increasing heating rate and exhibited a kinetic tendency. On the other hand, when the applied tensile stress was 25 MPa or more, the creep onset temperature temporarily decreased with an increase in the heating rate and turned to increase. This is a non-kinetic tendency different from that of thermal glass transition. It is presumed that in the creep process of metallic glass, in addition to the creep process due to thermal glass transition, another process suppressing creep is competing. © 2019 Japan Society of Corrosion Engineering.All right reserved.
引用
收藏
页码:218 / 220
页数:2
相关论文
共 10 条
[1]  
Inoue A., Stabilization of metallic supercooled liquid and bulk amorphous alloys, Acta Materialia, 48, 1, pp. 279-306, (2010)
[2]  
Suryanarayana C., Inoue A., Bulk Metallic Glasses, pp. 487-489, (2010)
[3]  
Yashiro W., Noda D., Hattori T., Hayashi K., Momose A., Kato H., A metallic glass grating for x-ray grating interferometers fabricated by imprinting, Applied Physics Express, 7, 3, pp. 0325011-0325013, (2014)
[4]  
Sadeghilaridjani M., Kato K., Shinohara T., Yashiro W., Momose A., Kato H., High aspect ratio grating by isochronal imprinting of less viscous workable Gd-based metallic glass for neutron phase imaging, Intermetallics, 78, pp. 55-63, (2016)
[5]  
Keryvin V., Vaillant M.L., Rouxel T., Huger M., Gloriant T., Kawamura Y., Thermal stability and crystallisation of a Zr55Cu30Al10Ni5 bulk metallic glass studied by in situ ultrasonic echography, Intermetallics, 10, 11-12, pp. 1289-1296, (2002)
[6]  
Kissinger H.E., Reaction kinetics in differential thermal analysis, Analytical Chemistry, 29, 11, pp. 1702-1706, (1957)
[7]  
Mehta N., Kumar A., Applicability of Kissinger's relation in the determination of activation energy of glass transition process, Journal of Optoelectronics and Advanced Materials, 7, 3, pp. 1473-1478, (2005)
[8]  
Koiwa M., Nakajima H., Zairyo ni okeru kakusan, (2009)
[9]  
Molar Volume for the Elements
[10]  
Hempel E., Hempel G., Hensel A., Schick C., Donth E., Characteristic length of dynamic glass transition near Tg for a wide assortment of glass-forming substances, Journal of Physical Chemistry B, 104, 11, pp. 2460-2466, (2000)