The development and challenges of poly (lactic acid) and poly (glycolic acid)

被引:461
作者
Jem K.J. [1 ,2 ]
Tan B. [3 ]
机构
[1] China Prosperity Green Industry Foundation, Ministry of Industry and Information Technology, 27 Wanshou Road, Room 2807, Building 1, Haidian District, 100846, Beijing
[2] Ningbo Institute of Materials Technology & Engineering, China Academy of Science, 1219 West Zhongguan Road, Zhenhai District, Ningbo, 315201, Zhejiang
[3] PJIM Polymer Scientific Co., Ltd., Room 615-618, T1, Lane 166, Minhong Road, Shanghai
关键词
Global warming; Modification of PLA with PGA; Plastic pollution; Poly (glycolic acid); Poly (lactic acid);
D O I
10.1016/j.aiepr.2020.01.002
中图分类号
学科分类号
摘要
Bio-plastics have gained tremendous attention, due to the increasing environmental pressure on global warming and plastic pollution. Among them, poly (lactic acid) (PLA) is both bio-based and bio-degradable, which has been widely used in many disposable packaging applications. The global market for PLA demand doubles every 3–4 years, as estimated by Jem's law. Compared to traditional petroleum-based plastics, PLA is more expensive and usually has less mechanical and physical properties. The recent compounding efforts and the commercialization of D(−) lactic acid and its polymer PDLA have the potential to improve the mechanical and thermal characteristics of PLA (e.g. by forming stereocomplex PLA) for applications in high-end markets. However, the usage of PLA in some other applications is still limited. With a structure similar to PLA, poly (glycolic acid) (PGA) has promising characteristics such as good biodegradability and barrier properties, which is potentially a beneficial supplement to PLA. The modification of PLA with PGA can be achieved via co-polymerization, physical blending and multilayer lamination. PGA and its combination with PLA have been widely studied in bio-medical applications, but not been well developed at large scales due to its relatively high production cost. In this case, the development of novel production technology and the advent of government regulations are the key drivers for the global transition towards bioplastics. Recently, multiple governmental regulations have been released that restrict the use of traditional plastics and facilitate bio-degradable plastic applications. PGA can be derived from industrial waste gases using an innovative production technology, which reduces carbon emissions and its production cost. By developing the production and compounding technology, PGA can be combined with PLA to play an essential role for a sustainable and environmental friendly plastic industry, especially for single-used products requiring fast degradation at room temperature or in the nature environment. © 2020 Kingfa SCI. & TECH. CO., LTD.
引用
收藏
页码:60 / 70
页数:10
相关论文
共 76 条
[61]  
Chu C.C., Hydrolytic degradation of polyglycolic acid: tensile strength and crystallinity study, Trans. Annu. Meet. Soc. Biomater. conjunction with Interna, 4, pp. 1727-1734, (1981)
[62]  
Hurrell S., Milroy G.E., Cameron R.E., The degradation of polyglycolide in water and deuterium oxide. Part I: the effect of reaction rate, Polymer, 44, 5, pp. 1421-1424, (2003)
[63]  
Montes De Oca H., Farrar D.F., Ward I.M., Degradation studies on highly oriented poly(glycolic acid) fibres with different lamellar structures, Acta Biomater., 7, 4, pp. 1535-1541, (2011)
[64]  
Milroy G.E., Et al., The degradation of polyglycolide in water and deuterium oxide. Part II: nuclear reaction analysis and magnetic resonance imaging of water distribution, Polymer, 44, 5, pp. 1425-1435, (2003)
[65]  
Hurrell S., Cameron R., Polyglycolide: degradation and drug release. Part I: changes in morphology during degradation, J. Mater. Sci. Mater. Med., 12, 9, pp. 811-816, (2001)
[66]  
Hurrell S., Milroy G., Cameron R., The distribution of water in degrading polyglycolide. Part I: sample size and drug release, J. Mater. Sci. Mater. Med., 14, 5, pp. 457-464, (2003)
[67]  
Ray S.S., Yamada K., Okamoto M., Ueda K., Biodegradable polylactide/montmorillonite nanocomposites, J. Nanosci. Nanotechnol., 3, 6, pp. 503-510, (2003)
[68]  
Ogata N., Jimenez G., Kawai H., Ogihara T., “Structure and thermal/mechanical properties of poly(l-lactide)-clay blend, J. Polym. Sci. B Polym. Phys., 35, 2, pp. 389-396, (1997)
[69]  
Matta A.K., Rao R.U., Suman K.N.S., Rambabu V., Preparation and characterization of biodegradable PLA/PCL polymeric blends, Procedia Mater. Sci., 6, pp. 1266-1270, (2014)
[70]  
Deng Y., Yu C., Wongwiwattana P., Thomas N.L., Optimising ductility of poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends through Co-continuous phase morphology, J. Polym. Environ., 26, 9, pp. 3802-3816, (2018)