Accelerated aging test and performance recovery analysis of PEMFC stack

被引:1
作者
Yang, Daijun [1 ,2 ]
Wang, Feijie [1 ,2 ]
Li, Bing [1 ,2 ]
Ma, Jianxin [1 ,2 ]
机构
[1] School of Automotive Studies, Tongji University, Shanghai
[2] Clean Energy Automotive Engineering Center, Tongji University, Shanghai
来源
Tongji Daxue Xuebao/Journal of Tongji University | 2015年 / 43卷 / 02期
关键词
Accelerated degradation test (ADT); Drive cycle; Performance recovery; Proton exchange membrane fuel cell(PEMFC);
D O I
10.11908/j.issn.0253-374x.2015.02.017
中图分类号
学科分类号
摘要
Accelerated degradation test (ADT) of a homemade kW-level proton exchange membrane fuel cell (PEMFC) stack was conducted under drive cycle. The stack performance degradation was observed, as expected, with the help of polarization curve, electrochemical impedance spectrum (EIS) and V-t curve. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were applied to characterize the fresh and post-experiment membrane electrode assemblies. The results show that after 603 h ADT, the max power output drops 21.6%. Meanwhile, the phenomenon of recoverable degradation after “rest” was preliminarily analyzed by virtue of EIS and equivalent circuit analysis. It is found that the values of constant phase angle element and faradic impedance get partly recovered, which implies that the recovery of the activity of catalyst and the hydrothermal environment in fuel cell reach an ideal condition before next cold-start. ©, 2015, Science Press. All right reserved.
引用
收藏
页码:273 / 279
页数:6
相关论文
共 24 条
[1]  
Xu S., Han W., Wang G., Et al., Hydrogen-recirculating ejector for proton exchange membrane fuel cell system: design and performance, Journal of Tongji University: Natural Science, 41, 1, (2013)
[2]  
Miller M., Bazylak A., A review of polymer electrolyte membrane fuel cellstack testing, Journal of Power Sources, 196, 2, (2011)
[3]  
Hydrogen and fuel cells program, DOE/EE-0651
[4]  
Wu J.F., Yuan X.Z., Jonathan J.M., Et al., A review of PEM fuel cell durability: degradation mechanismsand mitigation strategies, Journal of Power Sources, 184, 1, (2008)
[5]  
Lu L.G., Ouyang M.G., Huang H.Y., Et al., A semi-empirical voltage degradation model for a low-pressure proton exchange membrane fuel cell stack under bus city driving cycles, Journal of Power Sources, 164, 1, (2007)
[6]  
Lu X., Xu L., Wu M., Et al., Durability analysis of a proton exchange membrane fuel cell stack under simulated automobile working conditions, Chinese Journal of Power Sources, 33, 3, (2009)
[7]  
Bouchra W., Denis C., Xavier F., Et al., Comparison between two PEM fuel cell durability tests performed at constant current and under solicitations linked to transportmission profile, International Journal of Hydrogen Energy, 32, 17, (2007)
[8]  
Tang H., Qi Z.G., Manikandan R., Et al., PEM fuel cell cathode carbon corrosion due to theformation of air/fuel boundary at the anode, Journal of Power Sources, 158, 2, (2006)
[9]  
Seo D.H., Lee J.H., Park S.S., Et al., Investigation of MEA degradation in PEM fuel cell by on/off cyclic operation under different humid conditions, International Journal of Hydrogen Energy, 36, 2, (2011)
[10]  
Liang D., Shen Q., Hou M., Et al., Study of the cell reversal process of large area proton exchange membrane fuel cells under fuel starvation, Journal of Power Sources, 194, 2, (2009)