Thermokinetic investigation of the aluminum nanoparticles oxidation

被引：5
|
作者：
Vorozhtsov A.B. [1 ,2 ]
Rodkevich N.G. [3 ]
Bondarchuk I.S. [1 ]
Lerner M.I. [3 ,4 ]
Zhukov A.S. [1 ]
Glazkova E.A. [3 ]
Bondarchuk S.S. [1 ,5 ]
机构：
[1] Tomsk State University, av. Lenina 36, Tomsk
[2] Institute for Problems in Chemical and Energetic Technologies SB RAS, av. Socialisticheskaya 1, Biysk
[3] Institute of Physics Strength and Material Science, SB RAS, av. Akademicheskii 2/4, Tomsk
[4] Tomsk Polytechnic University, av. Lenina 30, Tomsk
[5] Tomsk State Pedagogical University, av. Kievskaya 60, Tomsk
来源：
International Journal of Energetic Materials and Chemical Propulsion | 2017年 / 16卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
Aluminum nanoparticles; Heterogeneous chemical reaction; Kinetic parameters; Non-isothermal regime; Organic reagents; Oxidation; Reaction mechanism; Thermogravimetric analysis;
D O I：
10.1615/IntJEnergeticMaterialsChemProp.2018022010
中图分类号：
学科分类号：
摘要：
The method to analyze the thermogravimetric data has been proposed. Based on the results of the analysis, the oxidation process was shown to include four stages of the oxidation stages. The kinetic parameters of the oxidation reactions were calculated for every stage of the oxidation process. These parameters were found to be determined by temperature parameters. The method was applied to the aluminum nanopowders encapsulated with organic reagents. The encapsulation was found to exert no influence on the oxidation reaction mechanism but does influence the influence on the oxidation rate at separate stages of the oxidation process. © 2017 by Begell House, Inc.
引用
收藏
页码：309 / 320
页数：11
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