Crystal Structure and Optical Properties of C 10 H 10 N 2 PbBr 4 and C 10 H 22 N 2 PbBr 4

被引：0
|
作者：
Kawahara, Mitsuyasu [1 ,3 ]
Teshima, Kenjiro. [2 ,3 ]
Rikukawa, Masahiro [1 ,3 ]
Sanui, Kohei. [1 ,3 ]
机构：
[1] Department of Chemistry, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo,102-8554, Japan
[2] Department of Photo-Optical Engineering, Tokyo Institute of Polytechnics, 1583, Iiyama, Kanagawa, Atsugi-shi,243-0297, Japan
[3] CREST, Japan Science and Technology Corporation (JST), 4-1-8, Hon-cho, Kawaguchi-shi, Saitama,332-0012, Japan
来源：
Molecular Crystals and Liquid Crystals | 2002年 / 376卷 / 01期
关键词：
Bromine compounds - Crystal structure - Optical data processing - Optical properties - organic-inorganic materials - Single crystals - X ray analysis;
D O I：
10.1080/713738416
中图分类号：
学科分类号：
摘要：
Novel organic-inorganic hybrid compounds, C 10 H 10 N 2 PbBr 4 and C 10 H 22 N 2 PbBr 4 were prepared and characterized by X-ray and optical measurements. The result of single crystal X-ray analysis showed that the inorganic region of C 10 H 10 N 2 PbBr 4 consisted of one-dimensional chains of line-sharing PbBr 6 octahedra, whereas that of C 10 H 22 N 2 PbBr 4 consisted of two-dimensional sheets of corner-sharing PbBr 6 octahedra. Each crystal exhibited an excitonic band at 307 nm for C 10 H 10 N 2 PbBr 4 and 383 nm for C 10 H 22 N 2 PbBr 4, which is attributed to the excitonic states of low-dimensional inorganic structures. These results indicate that the dimensional structure of these compounds can be systematically controlled by changing the chemical structure of organic ligands. © 2002, Copyright Taylor & Francis Group, LLC.
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页码：77 / 82
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