Preparation of High Performance Poly(lactic acid)/Polycaprolactone Composites by Die Drawing

被引:0
|
作者
Tang H. [1 ]
Fan B. [2 ]
Lan B. [1 ]
Luo X. [1 ]
Yang Q. [1 ]
机构
[1] State Key Laboratory of Polymer Materials Engineering, School of Polymer Science and Engineering, Sichuan University, Chengdu
[2] Qingdao Research Institute, Sichuan University, Qingdao
关键词
Die drawing; Polycaprolactone; Polylactic acid; Strengthening and toughening;
D O I
10.16865/j.cnki.1000-7555.2022.0111
中图分类号
学科分类号
摘要
The degradable polycaprolactone (PCL) was selected as toughening phase to improve the toughness of polylactic acid (PLA), and a reinforced and toughened highly oriented PLA/PCL composite material was prepared by die drawing. The effects of different PCL contents and the tensile field introduced by die drawing on the material structure and properties were studied. The results of SEM show that PCL is distributed in the PLA matrix in the form of fibers under the drawing action, and the interface contact increases and the interface interaction increases. The results of mechanical properties show that the strength of PLA composites is greatly enhanced while improving the toughness of PLA, and the strength of the sample after drawing is much higher than that of the undrawn sample. When the mass fraction of PCL is 10%, the tensile strength and modulus of the composites after die drawing reach 168.3 MPa and 5488.4 MPa, which are increased by 280% and 249.4% respectively compared with those of pure PLA; the elongation at break reaches 34% and is increased by 500%. © 2022, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码:89 / 93and101
相关论文
共 16 条
  • [1] Farah S, Anderson D G, Langer R., Physical and mechanical properties of PLA, and their functions in widespread applications-a comprehensive review, Advanced Drug Delivery Reviews, 107, pp. 367-392, (2016)
  • [2] Nofar M, Sacligil D, Carreau P J, Et al., Poly (lactic acid) blends: processing, properties and applications, International Journal of Biological Macromolecules, 125, pp. 307-360, (2019)
  • [3] Li T T, Zhang H, Huang S Y, Et al., Preparation and property evaluations of PCL/PLA composite films, Journal of Polymer Research, 28, pp. 336-345, (2021)
  • [4] Yokohara T, Yamaguchi M., Structure and properties for biomassbased polyester blends of PLA and PBS, European Polymer Journal, 44, pp. 677-685, (2008)
  • [5] Ostafinska A, Fortelny I, Nevoralova M, Et al., Synergistic effects in mechanical properties of PLA/PCL blends with optimized composition, processing, and morphology, RSC Advances, 5, pp. 98971-98982, (2015)
  • [6] Wu P, Yang Q, Zhao Z, Et al., Structure evolution and orientation mechanism of isotactic polypropylene during the two-stage solid die drawing process, Journal of Applied Polymer Science, 135, (2018)
  • [7] Zhang T, Wu P, Yang Q, Et al., Fabrication of reinforced and toughened poly(lactic acid)/poly(butylene adipate-coterephthalate) composites through solid die drawing process, Journal of Applied Polymer Science, 137, (2020)
  • [8] Yang H, Jiang S, Fang H, Et al., Molecular orientation in aligned electrospun polyimide nanofibers by polarized FT-IR spectroscopy, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 200, pp. 339-344, (2018)
  • [9] Li Y, Guo Z, Xue M, Et al., Epitaxial Recrystallization of IPBu in form II on an oriented IPS film initially induced by oriented form IIPBu, Macromolecules, 52, pp. 4232-4239, (2019)
  • [10] Sawai D, Takahashi K, Sasashige A, Et al., Preparation of oriented β-form poly(l-lactic acid) by solid-state coextrusion: effect of extrusion variables, Macromolecules, 36, pp. 3601-3605, (2003)