Preparation and properties of oxidized regenerated cellulose by hydrogen peroxide

被引：0

作者：

Zhang S. ^{[1
]}

Wang P. ^{[1
]}

Wu R. ^{[1
]}

Peng H. ^{[2
]}

Wu R. ^{[1
]}

机构：

[1] College of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou, 510640, Guangdong

[2] The Second Research Institute of Civil Aviation Administration of China, Chengdu, 610041, Sichuan

[3] College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046, Xinjiang

来源：

Huagong Xuebao/CIESC Journal | 2016年 / 67卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Adsorption; Carbonization; Hydrogen peroxide; Oxidized regenerated cellulose; Preparation;

D O I：

10.11949/j.issn.0438-1157.20151620

中图分类号：

学科分类号：

摘要：

Hydrogen peroxide was used to oxidize pretreated regenerated cellulose to oxidized regenerated cellulose (OGC) with carboxylic content (CC) ranging from 3.2% to 15.6% depending on the H2O2/cellulose molar ratios used, reaction time and the pH. The structure of OGC was characterized by FT-IR, 13C NMR, SEM,BET and XRD. The results revealed that the primary hydroxyl at C6 site in glucose units of regenerated cellulose was selectively oxidized to carboxyl group by H2O2 at the present of copper sulfate, and the notable characteristic peaks of carboxyl groups appeared at 173±2 in the spectra of 13C NMR. SEM revealed that the pretreated regenerated cellulose by alkali solution would increase the fiber diameter and grooves space, resulting in volume expansion of cellulose, and thereby promoting oxidation reaction. BET surface area (SBET) and adsorption pore volume (Vp) of OGC 15.6 increased from 10.12 m2·g-1 to 62.45 m2·g-1 and 0.0152 cm3·g-1 to 0.0183 cm3·g-1, respectively. The crystallinity of OGC showed increasing with the increase of CC, which was due to partial loss of the disordered regions during the washing process because of their increased water-solubility. By TG, there was a reduction in thermal stability in parallel with the increase in CC of the samples, while exhibited high char yields. These changes could be attributed to a reduction in degree of polymerization and the increment of CC. The results demonstrated that the cellulose was selectively oxidized to carboxyl group by H2O2, and the properties of OC were depended on the CC. The effect of carbonization agent type on the flame retardant properties of MFAPP/EP was investigated. It revealed that when OGC15.6 (6.25%) acted as carbonization agent, the epoxy resin achieved a UL-94 V0 classification with LOI of 27.2%. The flame retardant properties of MFAPP/EP by OGC15.6 were better than those of GC and pentaerythritol. The adsorption capacity of OGC for Cu2+ and Pb2+ ions from aqueous single metal solutions was obtained by analyzing concentration determined by atomic absorption spectroscopy. These samples showed maximum adsorption capacities for Cu2+ and Pb2+ ions ranging from 4.894 to 24.426 mg·g-1 and 5.845 to 71.833 mg·g-1, respectively. The OGC15.6 showed larger maximum adsorption capacities than GC. The result illuminated that OGC could be applied to flame retardant EP and metal ions adsorption due to the introduction of carboxylic group. © All Right Reserved.

引用

页码：2401 / 2409

页数：8

共 18 条

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