Correlation Between Glass Fiber Length and Flame Retardant Properties of LGF/PBT/RP Composites

被引:0
作者
Zhao W. [1 ]
He M. [1 ,2 ]
Zhang D. [1 ,2 ]
Huang T. [1 ]
Zhang L. [1 ]
机构
[1] College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang
[2] National Engineering Research Center for Compounding and Modification of Polymer Materials, Guiyang
来源
Cailiao Daobao/Materials Review | 2017年 / 31卷 / 04期
关键词
Composites; Effective length; Flame retardance; Long glass fiber; Polybutylene terephthalate; Pull-out length;
D O I
10.11896/j.issn.1005-023X.2017.07.022
中图分类号
TQ171 [玻璃工业];
学科分类号
摘要
The relationship between the glass fiber length and flame retardant of LGF/PBT/RP composites was studied. According to the analysis of optical microscope, combustion properties test, scanning electron microscope (SEM), dynamic thermomechanical analysis (DMA) and mechanical properties, it was found that with the initial length of glass fiber increasing, the effective fiber length distribution of LGF/PBT/RP composites firstly moved toward the longer region of glass fiber, then moved toward the shorter area of glass fiber.Moreover, the dispersion of glass fibers of LGF/PBT/RP composites turned from homogeneous to uneven. With increase of the length of glass fiber, the burning time of vertical burning test (UL-94), average heat release rate (Av-HRR), total smoke release (TSR), total heat release (THR), average effective heat of combustion(Av-EHC) and fire growth rate(FIGRA)of LGF/PBT/RP composite firstly decreased and then increased. The change trend of limiting oxygen index(LOI) was opposite. This behavior indicated that with the effective length of glass fiber increasing, the flame retardant performance of LGF/PBT/RP compo-site was improved, namely, the glass fiber length had an effect on flame retardant performance of LGF/PBT/RP composite. © 2017, Materials Review Magazine. All right reserved.
引用
收藏
页码:143 / 149
页数:6
相关论文
共 16 条
[1]  
Gao F., Tong L., Fang Z., Effect of a novel phosphorous-nitrogen containing intumescent flame retardant on the fire retardancy and the thermal behaviour of poly(butylene terephthalate), Polym Degrad Stab, 91, 91, (2006)
[2]  
Yang W., Hu Y., Tai Q., Et al., Fire and mechanical performance of nanoclay reinforced glass-fiber/PBT composites containing aluminum hypophosphite particles, Composites Part A: Appl Sci Manufacturing, 42, 7, (2011)
[3]  
Huang Q., The preparation and performance research of halogen-free flame retardant PBT engineering plastics, (2011)
[4]  
Lang L., Ye N., Li J., Et al., Flame retardancy and thermal stability of halogen-free flame retardant PBT, Plastics Sci Technol, 38, 6, (2010)
[5]  
Hartikainen J., Hine P., Szabo J.S., Polypropylene hybrid composites reinforced with long glass fibers and particulate filler, Compos Sci Technol, 65, 2, (2005)
[6]  
Chattopadhyay S.K., Khandal R.K., Uppaluri R., Et al., Influence of varying fiber lengths on mechanical, thermal, and morphological properties of MA-g-PP compatibilized and chemically modified short pineapple leaf fiber reinforced polypropylene composites, J Appl Polym Sci, 113, 6, (2009)
[7]  
Yang B., Leng J., He B., Et al., Influence of fiber length and compatibilizer on mechanical properties of long glass fiber reinforced polya-mide 6, 6, J Reinforced Plastics Compos, 31, 16, (2012)
[8]  
Tao Z., Wang Y., Li J., Et al., Fabrication of long glass fiber reinforced polyacetal composites: Mechanical performance, microstructures, and isothermal crystallization kinetics, Polym Compos, 36, 10, (2014)
[9]  
Huang H., Study on long glass fiber reinforced nylon 66 Composites, (2013)
[10]  
Casu A., Camino G., Giorgi M.D., Et al., Effect of glass fibres and fire retardant on the combustion behaviour of composites, glass fibres-poly(butylene terephthalate), Fire Mater, 22, 1, (1998)