EPR, 13C and 11B NMR of boronated carbons intercalated with heavy alkali metals (K, Rb and Cs)

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机构：
[1] Duclaux, L.
[2] Faugere, A.M.
[3] Conard, J.
[4] Flandrois, S.
[5] Lauginie, P.
来源：
Duclaux, L. | 2000年 / Gordon & Breach Science Publ Inc, Newark, NJ, United States卷 / 340期
关键词：
Ammonia - Boron - Carbon - Cesium - Chemical reactions - Chemical vapor deposition - Nuclear magnetic resonance spectroscopy - Paramagnetic resonance - Potassium - Rubidium;
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摘要：
BxC1-x host materials (0.1 13C and 11B NMR and EPR. 13C NMR shifts and EPR dysonian lines (typical of conductors) found in intercalation compounds are qualitatively similar to those observed in their GIC analogues. Evidence are reported in favor of a breaking of the local axial symmetry due to interstitial boron atoms for highest x values and partial recover of this symmetry in the intercalation compounds.
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