Research progress in separation and resource recovery of zinc and iron from spent galvanizing acid solution by solvent extraction

被引:1
作者
Feng, Xin [1 ]
Chu, Guojun [2 ]
Wang, Han [2 ]
Shi, Xiaolei [2 ]
Tu, Jiguo [1 ,3 ]
机构
[1] State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing
[2] Jilin Huaxin New Structure Technology Co., Ltd., Jilin
[3] Jianlong Group & USTB Joint Laboratory, University of Science and Technology Beijing, Beijing
来源
Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals | 2024年 / 34卷 / 07期
关键词
extraction mechanism; high-value product recovery; separation of zinc and iron; solvent extraction; spent galvanizing acid;
D O I
10.11817/j.ysxb.1004.0609.2023-44652
中图分类号
学科分类号
摘要
The spent galvanizing waste acid solution, which contains high concentration of ferrous salt, zinc salt and residual acid, has the characteristics of strong acidity, strong corrosiveness and difficult treatment. If the spent galvanizing waste acid solution cannot be effectively treated and directly discharged, it will cause significant damage to the surrounding environment and lead to serious resource waste. Solvent extraction is a potential treatment method for spent galvanizing waste acid, which has the characteristics of high selectivity, versatility and high product purity, especially in the treatment of waste liquid containing zinc ions. In this review, the extraction mechanism and influencing factors of treating spent galvanizing waste acid solution were comprehensively summarized under different acid-base extractant conditions, and the recovery of high value-added components from spent galvanizing waste acid solution was systematically expounded. Additionally, the development status of recycling spent galvanizing waste acid solution by solvent extraction was summarized, and the future research directions of efficient separation and recovery of zinc and iron were prospected. This review will provide important theoretical basis for the industrialization of related technologies, and promote the sustainable treatment and resource utilization of spent galvanizing waste acids. © 2024 Central South University of Technology. All rights reserved.
引用
收藏
页码:2383 / 2398
页数:15
相关论文
共 55 条
[11]  
PAN Z C, LI C., Research progress on treatment technology of wastewater containing zinc by adsorption method, Sichuan Chemical Industry, 16, 2, (2013)
[12]  
ZHU R L, LI X B, WEI C, Et al., Solvent extraction of zinc from Zn(Ⅱ)-NH<sub>4</sub>Cl-NH<sub>3</sub> complex solution using Mextral54-100, The Chinese Journal of Nonferrous Metals, 25, 4, (2015)
[13]  
XU C, ZHOU J, YIN S, Et al., Solvent extraction and separation of zinc-iron from spent pickling solution with tri-n-octylamine, Separation and Purification Technology, 278, (2021)
[14]  
PENG K B, GAO L K, RAO B, Et al., Current status of vanadium resources and research progress on vanadium extraction with organic phosphorus extractants, Chinese Journal of Engineering Science, 43, 5, (2021)
[15]  
MENG X, LIU T, HUO S, Et al., Separation of salicylic acid and two phenols by polyvinyl chloride/N, N-bis (1-methylheptyl) acetamide polymer inclusion membrane, Journal of Water Process Engineering, 41, (2021)
[16]  
ZHONG Y L, DENG C Y, SHI B, Et al., Synergistic solvent extraction of Ta/Nb/W from Ta/Nb extraction raffinate by using TBP and 2-octanol as extractants, The Chinese Journal of Nonferrous Metals, 31, 3, (2021)
[17]  
YONG H S, YI F L, XI H H, Et al., Recycling of residual valuable metals in cyanide-leached gold wastewater using the N263-TBP system, Journal of Environmental Chemical Engineering, 9, 6, (2021)
[18]  
SINHA M K, PRAMANIK S, SAHU S K, Et al., Development of an efficient process for the recovery of zinc and iron as value added products from the waste chloride solution[J], Separation and Purification Technology, 167, (2016)
[19]  
HU SX, XU C X, SRINIASAKANNAN C, Et al., Recovery of zinc and iron from hot-dip galvanizing spent pickle liquor using solvent extraction, Journal of Molecular Liquids, 362, (2022)
[20]  
SHAHAB A, MAHMOUD A, AHMAD D K, Et al., Theoretical and experimental comparison of rare earths extraction by [P6, 6, 6, 1, 4] [Decanoate] bifunctional ionic liquid and D2EHPA acidic extractant, Minerals Engineering, 180, (2022)