Reaction Kinetics of 3-methyl-3-butene-1-ol Synthesis in Supercritical Isobutylene without Catalysts

被引：0

作者：

Chen Z.-R. ^{[1
]}

Wan X.-F. ^{[1
]}

Yin H. ^{[1
]}

Yuan S.-F. ^{[1
]}

Wang Y. ^{[2
]}

机构：

[1] College of Chemical and Biological Engineering, Zhejiang University, Hangzhou

[2] Zhejiang NHU Company Ltd., Xinchang

来源：

Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2018年 / 32卷 / 06期

关键词：

Formaldehyde; Isobutylene; Supercritical; Uncatalyzed;

D O I：

10.3969/j.issn.1003-9015.2018.06.012

中图分类号：

学科分类号：

摘要：

3-methyl-3-butene-1-ol (MBOH) was synthesized in a batch stirred tank reactor using isobutylene and formaldehyde in supercritical isobutylene without catalysts at 513.15~543.15 K and 15~20 MPa. The structures of main products were characterized by gas chromatography-mass spectrometry (GC-MS) and nuclear magnetic resonance (NMR), and the main reaction network and corresponding kinetic model were established. The experimental data was fitted to obtain reaction rate constants of isobutylene-formaldehyde and MBOH-formaldehyde reactions under different temperatures. The results show that the activation energies of these two reactions are 101.95 and 83.99 kJ∙mol -1 , respectively. Increase of reaction temperature can enhance MBOH selectivity. © 2018, Editorial Board of Journal of Chemical Engineering of Chinese Universities". All right reserved."

引用

页码：1332 / 1337

页数：5

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