Effects of organic functionalization on glass transition temperature and toughness of epoxy resin composites reinforced by carbon nanotubes

被引:1
作者
Jiang C. [1 ]
Zhang J. [1 ]
Shang X. [1 ]
Lin S. [1 ]
Ju S. [1 ]
Jiang D. [1 ]
机构
[1] College of Aerospace Science and Engineering, National University of Defense Technology, Changsha
来源
Guofang Keji Daxue Xuebao/Journal of National University of Defense Technology | 2016年 / 38卷 / 01期
关键词
Carbon nanotubes; Epoxy resin; Glass transition temperature; Interphase; Organic functionalization; Toughness;
D O I
10.11887/j.cn.201601006
中图分类号
学科分类号
摘要
Different interphases between the carbon nanotubes and the epoxy resin were constructed through the organic functionalization of carbon nanotubes. Effects of different functionalized carbon nanotubes on the glass transition temperature of the epoxy resin composites were investigated by using the dynamic mechanical analysis method; the roughness of epoxy resin composites was studied in the pendulum impact test. Results show that: the glass transition temperature of the composites with amination carbon nanotube is the highest, while that of the composites with carboxylation carbon nanotube is lower than that of the pure epoxy resin; toughness of the composites with embedded carbon nanotubes is doubled. These variation laws in the properties are attributed to the different interphases formed between the functionalized carbon nanotubes and epoxy resin matrixes. © 2016, National University of Defense Technology. All right reserved.
引用
收藏
页码:34 / 38
页数:4
相关论文
共 13 条
[1]  
Han Z.D., Fina A., Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review, Progress in Polymer Science, 36, 7, pp. 914-944, (2011)
[2]  
Teng D., Jing J., Tian L., Et al., Research progress on carbon nanotube reinforced epoxy composites, Plastics Science and Technology, 39, 8, pp. 106-110, (2011)
[3]  
Vajtai R., Springer Handbook of Nanomaterials, (2013)
[4]  
Moniruzzaman M., Winey K.I., Polymer nanocomposites containing carbon nanotubes, Macromolecules, 39, 16, pp. 5194-5205, (2006)
[5]  
Rafiee R., Moghadam R.M., On the modeling of carbon nanotubes: a critical review, Composites Part B: Engineering, 56, pp. 435-449, (2014)
[6]  
Khare K.S., Khare R., Effect of carbon nanotube dispersion on glass transition in cross-linked epoxy/carbon nanotube nanocomposites: role of interfacial interactions, The Journal of Physical Chemistry B, 117, 24, pp. 7444-7454, (2013)
[7]  
Khare K.S., Khabaz F., Khare R., Effect of carbon nanotube functionalization on mechanical and thermal properties of cross-linked epoxy-carbon nanotube nanocomposites: role of strengthening the interfacial interactions, Acs Applied Materials & Interfaces, 6, 9, pp. 6098-6110, (2014)
[8]  
Chakraborty S., Roy S., Structural, dynamical, and thermodynamical properties of carbon nanotube polycarbonate composites: a molecular dynamics study, The Journal of Physical Chemistry B, 116, 10, pp. 3083-3091, (2012)
[9]  
Yoonessi M., Lebron-Colon M., Scheiman D., Et al., Carbon nanotube epoxy nanocomposites: the effects of interfacial modifications on the dynamic mechanical properties of the nanocomposites, Acs Applied Materials & Interfaces, 6, 19, pp. 16621-16630, (2014)
[10]  
Jiang C., Jiang D., Progress on modification of high performance resins for composites matrix, Polymer Materials Science and Engineering, 29, 10, pp. 187-190, (2013)