Synergistic Effect of Magnesium Hydroxystannate with Intumescent Flame Retardants on Thermal and Fire Safety Properties of Polypropylene

被引:3
作者
Sheng H. [1 ]
Wang B. [1 ]
Song L. [1 ]
Hu W. [1 ]
Hong N. [1 ]
Hu Y. [1 ,2 ]
机构
[1] State Key Laboratory of Fire Science, University of Science and Technology of China, Anhui
[2] Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study, University of Science and Technology of China, Suzhou, Jiangsu
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Intumescent flame retardant; magnesium hydroxystannate; Polypropylene;
D O I
10.1080/03602559.2015.1055497
中图分类号
学科分类号
摘要
Magnesium hydroxystannate [MgSn(OH)6, MgHS] was successfully prepared by a facile coprecipitation method. Then, MgHS was used to intumescent flame-retardant polypropylene systems. Thermogravimetry analysis results indicated that the introduction of MgHS can improve the thermal stability of the intumescent flame-retardant polypropylene system. Limiting oxygen index and UL-94 vertical burning test data show that the addition of MgHS can significantly improve the flame retardancy of intumescent flame-retardant polypropylene system. From the cone calorimetry results, it can be observed that the peak heat release rate is decreased in comparison with intumescent flame-retardant polypropylene. Moreover, the addition of MgHS significantly reduced the gaseous products, especially carbon monoxide. © 2016, Copyright © Taylor & Francis Group, LLC.
引用
收藏
页码:36 / 45
页数:9
相关论文
共 29 条
[1]  
Shi Y., Qian X., Zhou K., Tang Q., Jiang S., Wang B., Wang B., Yu B., Hu Y., Yuen R.K.K., CuO/graphene nanohybrids: Preparation and enhancement on thermal stability and smoke suppression of polypropylene, Ind. Eng. Chem. Res, 52, pp. 13654-13660, (2013)
[2]  
Chiu S.-H., Wang W.-K., Dynamic flame retardancy of polypropylene filled with ammonium polyphosphate, pentaerythritol and melamine additives, Polymer, 39, pp. 1951-1955, (1998)
[3]  
Yang R., Zhao J., Liu Y., Oxidative degradation products analysis of polymer materials by pyrolysis gas chromatography–mass spectrometry, Polym. Degrad. Stabil, 98, pp. 2466-2472, (2013)
[4]  
Chen Y., Liu Y., Wang Q., Yin H., Aelmans N., Kierkels R., Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: Effect of component ratio, Polym. Degrad. Stabil, 81, pp. 215-224, (2003)
[5]  
Nie S., Hu Y., Song L., He S., Yang D., Study on a novel and efficient flame retardant synergist–nanoporous nickel phosphates VSB-1 with intumescent flame retardants in polypropylene, Polym. Adv. Technol, 19, pp. 489-495, (2008)
[6]  
Zhou K., Jiang S., Wang B., Shi Y., Liu J., Hong N., Hu Y., Gui Z., Combined effect of transition metal phosphide (MxPy, M = Ni, Co, and Cu) and intumescent flame retardant system on polypropylene, Polym. Adv. Technol, 25, pp. 701-710, (2014)
[7]  
Wang L., Hu Y., Song L., Yuen R.K.K., Investigation of thermal and combustion properties for intumescent flame-retardant ethylene–viny acetate composites containing ferrous disulfide, Ind. Eng. Chem. Res, 51, pp. 15082-15088, (2012)
[8]  
Lv P., Wang Z., Hu Y., Yu M., Effect of metallic oxides in polypropylene composites containing melamine phosphate and pentaerythritol, Plast. Rubber. Compos, 37, pp. 311-318, (2008)
[9]  
Wu J., Hu Y., Song L., Kang W., Synergistic effect of lanthanum oxide on intumescent flame-retardant polypropylene-based formulations, J. Fire. Sci, 26, pp. 399-414, (2008)
[10]  
Nie S., Song L., Bao C., Qian X., Guo Y., Hong N., Hu Y., Synergistic effects of ferric pyrophosphate (FePP) in intumescent flame-retardant polypropylene, Polym. Adv. Technol, 22, pp. 870-876, (2011)